Zeolites in adsorption processes: State of the art and future prospects

E Pérez-Botella, S Valencia, F Rey - Chemical Reviews, 2022 - ACS Publications
Zeolites have been widely used as catalysts, ion exchangers, and adsorbents since their
industrial breakthrough in the 1950s and continue to be state-of the-art adsorbents in many …

Single-atom catalysts across the periodic table

SK Kaiser, Z Chen, D Faust Akl, S Mitchell… - Chemical …, 2020 - ACS Publications
Isolated atoms featuring unique reactivity are at the heart of enzymatic and homogeneous
catalysts. In contrast, although the concept has long existed, single-atom heterogeneous …

Molecular views on mechanisms of Brønsted acid-catalyzed reactions in zeolites

C Chizallet, C Bouchy, K Larmier… - Chemical …, 2023 - ACS Publications
The Brønsted acidity of proton-exchanged zeolites has historically led to the most impactful
applications of these materials in heterogeneous catalysis, mainly in the fields of …

Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Catalysis in a cage: condition-dependent speciation and dynamics of exchanged Cu cations in SSZ-13 zeolites

C Paolucci, AA Parekh, I Khurana… - Journal of the …, 2016 - ACS Publications
The relationships among the macroscopic compositional parameters of a Cu-exchanged
SSZ-13 zeolite catalyst, the types and numbers of Cu active sites, and activity for the …

Intergrowth zeolites, synthesis, characterization, and catalysis

Y Wang, C Tong, Q Liu, R Han, C Liu - Chemical Reviews, 2023 - ACS Publications
Microporous zeolites that can act as heterogeneous catalysts have continued to attract a
great deal of academic and industrial interest, but current progress in their synthesis and …

Multi-scale complexities of solid acid catalysts in the catalytic fast pyrolysis of biomass for bio-oil production–A review

R Liu, M Sarker, MM Rahman, C Li, M Chai… - Progress in Energy and …, 2020 - Elsevier
Despite remarkable progress in catalytic fast pyrolysis, bio-oil production is far from
commercialization because of multi-scale challenges, and major constraints lie with …

Analysis and control of acid sites in zeolites

A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
The exceptional catalytic performance of zeolites is due to the presence of active sites in a
shape-selective environment, ie, in micropores with molecular dimensions. The present …

Controlling the isolation and pairing of aluminum in chabazite zeolites using mixtures of organic and inorganic structure-directing agents

JR Di Iorio, R Gounder - Chemistry of Materials, 2016 - ACS Publications
Synthetic methods are reported to prepare chabazite (CHA) zeolites (SSZ-13) at fixed
elemental composition but with different arrangements of their framework Al atoms (Al–O …

Engineering zeolites for catalytic cracking to light olefins

V Blay, B Louis, R Miravalles, T Yokoi… - ACS …, 2017 - ACS Publications
Propene is a key building block for the petrochemical industry whose demand is increasing
strongly in recent years, even faster than that of ethene. The availability of propene is limited …