Cluster-based single-molecule magnets

CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …

Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue

EE Moushi, C Lampropoulos… - Journal of the …, 2010 - ACS Publications
The syntheses, crystal structures, and magnetic properties of a new family of heterometallic
Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of …

Mn8 and Mn16 Clusters from the Use of 2-(Hydroxymethyl)pyridine, and Comparison with the Products from Bulkier Chelates: A New High Nuclearity Single …

T Taguchi, W Wernsdorfer, KA Abboud… - Inorganic …, 2010 - ACS Publications
The synthesis, crystal structures, and magnetochemical characterization of two new Mn
clusters [Mn8O2 (O2CPh) 10 (hmp) 4 (MeOH) 2](1; 6MnII, 2MnIII) and [Mn16O8 (OH) 2 …

A [Mn8] Defective Supertetrahedron T3 and Its Dimeric [Mn16] Analogue

A Anastassiades, DI Alexandropoulos… - Crystal Growth & …, 2024 - ACS Publications
The initial use of 2-(pyridin-2-yl) propane-1, 3-diol (pypdH2) in Mn cluster chemistry has
afforded two new mixed-valence polynuclear Mn clusters, namely,[Mn8Ο5 (pypd)(hmp) 3 …

Body-wing swapping in butterfly {Fe III 2 Ln III 2} coordination clusters with triethylene glycol as ligand

G Peng, GE Kostakis, Y Lan, AK Powell - Dalton Transactions, 2013 - pubs.rsc.org
The first use of triethylene glycol (H2teg) in Fe/Ln chemistry affords two series of tetranuclear
{FeIII2LnIII2} coordination clusters possessing defect-dicubane cores. A change in the …

New Mixed-Valent Mn Clusters from the Use of N,N,N′,N′-Tetrakis(2-hydroxyethyl)ethylenediamine (edteH4): Mn3, Mn4, Mn6, and Mn10

A Saha, KA Abboud, G Christou - Inorganic Chemistry, 2011 - ACS Publications
The syntheses, crystal structures, and magnetochemical characterization are reported for the
new mixed-valent Mn clusters [Mn2IIMnIII (O2CMe) 2 (edteH2) 2](ClO4)(1),[MnII2MnIII2 …

Phosphorus-based ligand effects on the structure and radical scavenging ability of molecular nanoparticles of CeO 2

B Russell-Webster, J Lopez-Nieto, KA Abboud… - Dalton …, 2021 - pubs.rsc.org
Two new CeIV/O2− clusters,(pyH) 8 [Ce10O4 (OH) 4 (O3PPh) 12 (NO3) 12](1) and [Ce6O4
(OH) 4 (O2PPh2) 4 (O2CtBu) 8](2), have been prepared that contain P-based ligands for the …

Theoretical Elucidation of Geometrical Structures of the CaMn4O5 Cluster in Oxygen Evolving Complex of Photosystem II Scope and Applicability of Estimation …

M Shoji, H Isobe, S Yamanaka, Y Umena… - Advances in quantum …, 2019 - Elsevier
Atmospheric oxygenation and evolution of aerobic life on our earth are a result of water
oxidation by oxygenic photosynthesis in photosystem II (PSII) of plants, algae, and …

The remarkable influence of N, O-ligands in the assembly of a bis-calix [4] arene-supported [Mn IV2 Mn III10 Mn II8] cluster

M Coletta, S Sanz, LJ McCormick, SJ Teat… - Dalton …, 2017 - pubs.rsc.org
Calix [4] arenes are versatile ligands, capable of supporting the formation of a wide variety of
polymetallic clusters comprising 3d, 4f or 3d–4f metal ions. Calixarene-based metal ion …

ST = 22 [Mn10] Supertetrahedral Building-Block to Design Extended Magnetic Networks

G Wu, J Huang, L Sun, J Bai, G Li… - Inorganic …, 2011 - ACS Publications
The controlled organization of high-spin complexes, eventually single-molecule magnets, is
a great challenge in molecular sciences to probe the possibility to design sophisticated …