Probing Substrate Transport Effects on Enzymatic Hydrogen Catalysis: An Alternative Proton Transfer Pathway in Putatively Sensory [FeFe] Hydrogenase
[FeFe] hydrogenases, metalloenzymes catalyzing proton/dihydrogen interconversion, have
attracted intense attention due to their remarkable catalytic properties and (bio-) …
attracted intense attention due to their remarkable catalytic properties and (bio-) …
The missing pieces in the catalytic cycle of [FeFe] hydrogenases
MT Lachmann, Z Duan, P Rodríguez-Maciá… - Chemical …, 2024 - pubs.rsc.org
Hydrogen could provide a suitable means for storing energy from intermittent renewable
sources for later use on demand. However, many challenges remain regarding the activity …
sources for later use on demand. However, many challenges remain regarding the activity …
Embedding biocatalysts in a redox polymer enhances the performance of dye-sensitized photocathodes in bias-free photoelectrochemical water splitting
F Cheng, O Pavliuk, S Hardt, LA Hunt, B Cai… - Nature …, 2024 - nature.com
Dye-sensitized photoelectrodes consisting of photosensitizers and molecular catalysts with
tunable structures and adjustable energy levels are attractive for low-cost and eco-friendly …
tunable structures and adjustable energy levels are attractive for low-cost and eco-friendly …
Synthesis, Spectroscopy, and Structure of [FeRu(μ-dithiolate)(CN)2(CO)4]2–
The salt [K (18-crown-6)] 2 [Ru (CN) 2 (CO) 3]([K (18-crown-6)] 2 [1]) was generated by the
reaction of Ru (C2H4)(CO) 4 with [K (18-crown-6)] CN. An initial thermal reaction gives [Ru …
reaction of Ru (C2H4)(CO) 4 with [K (18-crown-6)] CN. An initial thermal reaction gives [Ru …
Probing the Influence of the Protein Scaffold on H-Cluster Reactivity via Gain-of-Function Studies─Improved H2 Evolution and O2 Tolerance through Rational …
[FeFe] hydrogenases make up a structurally diverse family of metalloenzymes that catalyze
proton/dihydrogen interconversion. They can be classified into phylogenetically distinct …
proton/dihydrogen interconversion. They can be classified into phylogenetically distinct …
Oxygen sensitivity of [FeFe]-hydrogenase: a comparative study of active site mimics inside vs. outside the enzyme
[FeFe]-hydrogenase is nature's most efficient proton reducing and H2-oxidizing enzyme.
However, biotechnological applications are hampered by the O2 sensitivity of this …
However, biotechnological applications are hampered by the O2 sensitivity of this …
Putting cyaphide in its place: determining the donor/acceptor properties of the κ C-cyaphido ligand
ES Yang, E Combey, JM Goicoechea - Chemical Science, 2023 - pubs.rsc.org
The synthesis of group 9 pyridine–diimine complexes M (DippPDI) X and [M (DippPDI)
L]+(M= Co, Rh; DippPDI= 1, 1′-(pyridine-2, 6-diyl) bis (N-(2, 6-diisopropylphenyl) ethan-1 …
L]+(M= Co, Rh; DippPDI= 1, 1′-(pyridine-2, 6-diyl) bis (N-(2, 6-diisopropylphenyl) ethan-1 …
Mining Nature's Platinum: Discovery, Characterization, and Optimization of Hydrogenases for Green H2 Applications
PR Cabotaje - 2024 - diva-portal.org
Abstract Cabotaje, PR 2024. Mining Nature's Platinum. Discovery, Characterization, and
Optimization of Hydrogenases for Green H2 Applications. Digital Comprehensive …
Optimization of Hydrogenases for Green H2 Applications. Digital Comprehensive …
Novel bioinspired and biohybrid electrode materials for hydrogen production
A Zamader - 2023 - theses.hal.science
Hydrogenase enzymes were first discovered in the 1930s. The first report of {Fe2 (μ-S2)(CO)
6} based catalyst was reported in 1928 without any information of [FeFe] hydrogenases. The …
6} based catalyst was reported in 1928 without any information of [FeFe] hydrogenases. The …
[PDF][PDF] Nouveaux matériaux d'électrode bioinspirés et biohybrides pour la production d'hydrogène Novel bioinspired and biohybrid electrode materials for hydrogen …
A ZAMADER - theses.hal.science
Cette thèse a été réalisée dans le cadre du projet eSCALED administré par le programme
MSCA horizon 2020 de l'UE, qui visait à développer un dispositif appelé" feuille artificielle" …
MSCA horizon 2020 de l'UE, qui visait à développer un dispositif appelé" feuille artificielle" …