Foldamer-Based Mechanoresponsive Materials: Molecular Nanoarchitectonics to Advanced Functions

D Talukdar, B Gole - Langmuir, 2024 - ACS Publications
Artificial molecules that respond to external stimuli such as light, heat, chemical signals, and
mechanical force have garnered significant interest due to their tunable functions, variable …

Validation of an accurate and expedient initial rates method for characterizing mechanophore reactivity

ME McFadden, AC Overholts, SK Osler… - ACS Macro …, 2023 - ACS Publications
Understanding structure–mechanochemical reactivity relationships is important for informing
the rational design of new stimuli-responsive polymers. To this end, establishing accurate …

Diverse reactivity of maleimides in polymer science and beyond

BE Kirkpatrick, KS Anseth, TS Hebner - Polymer International, 2024 - Wiley Online Library
Maleimides are remarkably versatile functional groups, capable of participating in homo‐
and copolymerizations, Diels–Alder and (photo) cycloadditions, Michael additions, and other …

Advancing the Mechanosensitivity of Atropisomeric Diarylethene Mechanophores through a Lever-Arm Effect

C Zhang, TB Kouznetsova, B Zhu… - Journal of the …, 2024 - ACS Publications
Understanding structure–mechanical activity relationships (SMARs) in polymer
mechanochemistry is essential for the rational design of mechanophores with desired …

Highly Thermal Stable, Stiff, and Recyclable Self-Healing Epoxy Based on Diels–Alder Reaction

J Wang, D Chen, S Xing, B Ji, J Yang… - ACS Applied Polymer …, 2023 - ACS Publications
The low heat resistance of self-healing polymers based on the Diels–Alder (DA) reaction
between 2-substituted furans with maleimide has significantly limited their practical …

Versatile Mechanochemical Reactions Via Tailored Force Transmission in Mechanophores

D Xu, W Liu, S Tian, H Qian - Angewandte Chemie, 2025 - Wiley Online Library
In polymer mechanochemistry, regulating the intrinsic mechanical reactivity of a
mechanophore offers extensive opportunities in material science, enabling the development …

Oriented External Electric Field Controls the Rupture Forces in Mechanophores

A Das, A Datta - The Journal of Physical Chemistry B, 2024 - ACS Publications
Controlling the reactivity of molecules under a mechanical pull has generated significant
interest in organic and polymer chemistry. Inducing mechano-lability for otherwise rigid …

Quantitative Connection between Macroscopic Stress and Bond-Breaking Force Enabled by Time-Stamped Mechanochemical Fluorescence

J Wang, Z Wang, D Sathe, MC Wang, J Zhou, Z Ling… - 2025 - researchsquare.com
Mechanical stress is ubiquitous in materials, and it is well accepted that stress causes
material wear and failure—which, at the molecular level, results from force-induced bond …