Halogen⋯ halogen interactions: nature, directionality and applications

BK Saha, RVP Veluthaparambath… - Chemistry–An Asian …, 2023 - Wiley Online Library
Halogen⋯ halogen interaction is a highly debated and important topic in crystal engineering
and supramolecular chemistry. There are controversies about the nature and geometry of …

An elastic organic crystal enables macroscopic photoinduced crystal elongation

YS Chen, CH Wang, YH Hu, CYD Lu… - Journal of the American …, 2023 - ACS Publications
Among the various types of photomechanical deformations of organic crystals, photoinduced
elongation of millimeter-scale crystals has yet to be demonstrated. Here we report that the …

Schiff base flexible organic crystals toward multifunctional applications

XH Ding, LZ Wang, YZ Chang, CX Wei, JY Lin… - …, 2024 - Wiley Online Library
The emergence of flexible organic crystals changed the perception of molecular crystals that
were regarded as brittle entities over a long period of time, and sparked a great interest in …

Elasto-plastic behaviour with reversible thermosalient expansion in acrylonitrile-based organic crystals

D Manoharan, S Ranjan, F Emmerling… - Journal of Materials …, 2024 - pubs.rsc.org
Crystalline materials that exhibit reversible mechanical responses upon exposure to
external stimuli have garnered significant attention owing to their potential applications in …

Tailoring enhanced elasticity of crystalline coordination polymers

O Mišura, M Pisacic, M Borovina… - Crystal growth & …, 2023 - ACS Publications
The approach for enhancing the elasticity of crystals with suboptimal elastic performances
through a rational design was presented. A hydrogen-bonding link was identified as a …

Designing the mechanical plasticity of benzylidene indanones based molecular crystals by crystal engineering

D Manoharan, M SN, MSRN Kiran… - Crystal Growth & …, 2023 - ACS Publications
We herein report the tuning of mechanical plasticity of a series of 2-benzylidene-1-indanone
derivative crystals through controlling intermolecular interactions for the first time. The roles …

Multi-flexible organic crystal responding to different mechanical forces for flexible optical waveguides

K Chen, J Wang, W Wu, H Shan, H Zhao, N Wang… - Dyes and …, 2023 - Elsevier
Organic crystals with flexibility have been a research hotspot due to their huge potential in
flexible optoelectronics. However, most organic crystals are brittle, which greatly restricts …

A flexible organic single crystal with room temperature phosphorescent waveguide and piezochromism properties

J Peng, J Yang, A Li - Dyes and Pigments, 2024 - Elsevier
Flexible crystals with plasticity and elasticity that exhibit phosphorescent emission are quite
rare yet highly significant for their potential applications. In our study, we present an example …

Integrating 2D elasticity and elastoplasticity into a multi-stimuli-responsive crystal through phase transitions

Y Hou, P Yang, J Zhao, J Fu, C Wang, Y Shi… - Journal of Materials …, 2023 - pubs.rsc.org
Practical applications of flexible crystals are often limited due to their monotonous
properties. In this study, multi-stimuli-responsive crystals of isonicotinamide (INA), which …

Crystal property engineering using molecular–supramolecular equivalence: mechanical property alteration in hydrogen bonded systems

S Mondal, CM Reddy, S Saha - Chemical Science, 2024 - pubs.rsc.org
Most crystal engineering strategies exercised until now mainly rely on the alteration of weak
non-covalent interactions to design structures and thus properties. Examples of mechanical …