Green Energy by Hydrogen Production from Water Splitting, Water Oxidation Catalysis and Acceptorless Dehydrogenative Coupling

JA Luque-Urrutia, T Ortiz-García, M Solà, A Poater - Inorganics, 2023 - mdpi.com
In this review, we want to explain how the burning of fossil fuels is pushing us towards green
energy. Actually, for a long time, we have believed that everything is profitable, that …

Primary Amine Nucleophilic Addition to Nitrilium Closo-Dodecaborate [B12H11NCCH3]: A Simple and Effective Route to the New BNCT Drug Design

AV Nelyubin, NA Selivanov, AY Bykov… - International Journal of …, 2021 - mdpi.com
In the present work, a convenient and straightforward approach to the preparation of
borylated amidines based on the closo-dodecaborate anion [B12H11NCCH3NHR]−, R= H …

Mechanism of the manganese-pincer-catalyzed acceptorless dehydrogenative coupling of nitriles and alcohols

JA Luque-Urrutia, M Solà, D Milstein… - Journal of the American …, 2019 - ACS Publications
A recent study showed that a Mn-pincer could catalyze the acceptorless dehydrogenative
coupling of nitriles and alcohols to yield acrylonitriles. The reaction mechanism proposed in …

Isoxazole strategy for the synthesis of α-aminopyrrole derivatives

EE Galenko, SA Linnik, OV Khoroshilova… - The Journal of …, 2019 - ACS Publications
The synthesis of methyl 5-aminopyrrole-3-carboxylates from 4-methyleneisoxazol-5-ones
via “cyanide Michael addition/methylation/reductive isoxazole-pyrrole transformation” is …

Recent Advances in the Green Synthesis of Heterocycles: From Building Blocks to Biologically Active Compounds

C Schäfer, H Cho, B Vlocskó, G Xie… - Current Organic …, 2022 - ingentaconnect.com
Recent advances in the environmentally benign synthesis of common heterocycles are
described. This account features three main parts; the preparation of non-aromatic …

Ring Opening of Donor–Acceptor Cyclopropanes with Cyanide Ion and Its Surrogates

MA Boichenko, IA Andreev… - The Journal of …, 2019 - ACS Publications
A straightforward method for ring opening of donor–acceptor cyclopropanes with
trimethylsilyl cyanide as a surrogate of cyanide ion in the presence of B (C6F5) 3 or …

Visible-Light-Mediated Remote γ-C(sp3)–H Functionalization of Alkylimidates: Synthesis of 4-Iodo-3,4-dihydropyrrole Derivatives

Y Kumar, Y Jaiswal, A Kumar - Organic letters, 2018 - ACS Publications
An efficient and environmentally friendly synthetic approach toward functionalized
dihydropyrrole derivatives is reported. The developed protocol proceeds via chemoselective …

Short and Modular Synthesis of Substituted 2-Aminopyrroles

R Diana-Rivero, B Halsvik, F Garcia Tellado… - Organic …, 2021 - ACS Publications
We herein describe a simple and metal-free domino methodology to synthesize 2-
aminopyrroles from alkynyl vinyl hydrazides. The domino reaction involves a novel …

A cascade reaction of indolyl-migratory isocyanide insertion, scaffold rearrangement and redox-neutral event with isocyanide as a C (sp3) H–N synthon efficiently …

S Sisodiya, A Acharya, M Nagpure, N Roy… - Chemical …, 2022 - pubs.rsc.org
Herein, we report a Pd (0)-catalyzed cascade reaction of intramolecular indolyl isocyanide-
insertion, isocyanide-initiated scaffold-rearrangement with indolyl migration and redox …

One-Pot Synthesis of Unprotected 2-Acylpyrroles from 1,2,3-Triazoles and 2-Hydroxymethylallyl Carbonates

JU Park, LZ Huang, HJ Cho, BY Park… - The Journal of Organic …, 2022 - ACS Publications
An efficient, tandem one-pot approach to synthesize multisubstituted 2-acylpyrroles from
readily prepared N-tosyl triazoles and 2-hydroxymethylallyl carbonates is reported. The …