Atranes are comprised of two bridgehead atoms bridged by three three-atom moieties.
When the bridgehead atoms interact, a [3.3. 3.0] tricyclic system is produced; when they do …

Nucleophilic displacement reactions at tetracoordinated phosphorus1-9 and silicon9-13 are
commonly discussed in terms of mechanisms involving pentacoordinated activated states …

No neutral silicon Lewis super acids are known to date. We report on the synthesis of bis
(perchlorocatecholato) silane and verify its Lewis super acidity by computation (DLPNO …

The question of how closely do the properties of organic compounds of silicon resemble
those of derivatives of its congener carbon atom was raised more than a century ago. A …

Aryl silatranes undergo fluoride-induced cross-coupling with aryl triflates to provide
unsymmetrical biaryl derivatives in good to excellent yields. Silatranes also couple with aryl …

On the basis of the high-resolution single-crystal X-ray diffraction data and theoretical
B3LYP/6-311+ G (d) and B3LYP/cc-pVDZ calculations, the electron density distribution in …

A new class of silatranes N [CH2 (Me2C6H2) O] 3SiR was prepared by the reaction of
organosilanes with tris (2-hydroxy-4, 6-dimethylbenzyl) amine (5) in the case of 1, 3, and 4 …

Bisher sind noch keine neutralen Silicium‐Lewis‐Supersäuren bekannt. Wir berichten hier
über die Synthese des Bis (perchlorocatecholato) silans und bestätigen dessen Lewis …

In silicon compounds the Si atoms are known to be fourfold coordinated in most cases.
However, there are several cationic, anionic, and neutral molecular species containing …

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