Filling gaps in asymmetric hydrogenation methods for acyclic stereocontrol: application to chirons for polyketide-derived natural products
The large volume of research studying hydrogenation catalysis might suggest that
stereoselective hydrogenation of alkenes is a solved problem, but we believe the most …
stereoselective hydrogenation of alkenes is a solved problem, but we believe the most …
A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes
HA Malik, GJ Sormunen… - Journal of the American …, 2010 - ACS Publications
A strategy for catalyst-controlled regioselectivity in aldehyde− alkyne reductive couplings
has been developed. This strategy is the first where either regiochemical outcome may be …
has been developed. This strategy is the first where either regiochemical outcome may be …
Reaction design, discovery, and development as a foundation to function-oriented synthesis
GC Micalizio, SB Hale - Accounts of chemical research, 2015 - ACS Publications
Conspectus Convergent C–C bond-forming reactions define the fabric of organic synthesis
and, when applied in complex molecule synthesis, can have a profound impact on efficiency …
and, when applied in complex molecule synthesis, can have a profound impact on efficiency …
Enantioselective Synthesis of anti- and syn-Homopropargyl Alcohols via Chiral Brønsted Acid Catalyzed Asymmetric Allenylboration Reactions
M Chen, WR Roush - Journal of the American Chemical Society, 2012 - ACS Publications
Chiral Brønsted acid catalyzed asymmetric allenylboration reactions are described. Under
optimized conditions, anti-homopropargyl alcohols 2 are obtained in high yields with …
optimized conditions, anti-homopropargyl alcohols 2 are obtained in high yields with …
Efficient Organocatalytic Hetero-Diels-Alder Reactions of Activated Ketones under High Pressure for Direct Access to δ-Lactones
K Mori, J Maddaluno, K Nakano, Y Ichikawa, H Kotsuki - Synlett, 2009 - thieme-connect.com
A general and efficient protocol for the high-pressure-promoted hetero-Diels-Alder reactions
of activated ketones has been developed. The reactions are successfully achieved by …
of activated ketones has been developed. The reactions are successfully achieved by …
[引用][C] 29.9. 2.1 Synthesis by Formation of Two C—O Bonds: Cyclization of Dihydroxy Ketones
EA Anderson, B Gockel - Science of Synthesis Knowledge Updates 2010 …, 2014 - Thieme