We present an update and revision to our 2010 review on the topic of proton-coupled
electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and …

An efficient nitrogen fixation reaction is highly desirable for obtaining the essential chemicals
and energy carriers but remains a challenge due to the strong nonpolar bonding and …

Nitrogenases are responsible for biological nitrogen fixation, a crucial step in the
biogeochemical nitrogen cycle. These enzymes utilize a two-component protein system and …

We report the synthesis of nanostructured Fe3S4 from deep eutectic solvents via a one-step
solvothermal method. The as-obtained Fe3S4 catalyst was capable of electrochemically …

We have recently reported on several Fe catalysts for N2-to-NH3 conversion that operate at
low temperature (− 78° C) and atmospheric pressure while relying on a very strong …

Despite the critical role Ru and Os complexes have played in the development of transition
metal dinitrogen chemistry, they have not been shown to mediate catalytic N2-to-NH3 …

We present a systematic investigation of the structural and electronic changes that occur in
an Fe (0)–N2 unit (Fe (depe) 2 (N2); depe= 1, 2-bis (diethylphosphino) ethane) upon the …

Transition metals form a variety of alkylidyne complexes with either a d0 metal center (high-
valent) or a non-d0 metal center (low-valent). One of the most interesting properties of …

Local electric fields can alter energy landscapes to impart enhanced reactivity in enzymes
and at surfaces. Similar fields can be generated in molecular systems using charged …

Active catalysts for nitrogen fixation (N2-fixation) have been widely pursued through
constant efforts for industrial applications. Here, we report a family of catalysts, MXenes …