The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …

The past decade has witnessed some remarkable advances in our appreciation of the
structural and reaction chemistry of the heavier alkaline earth (Ae= Mg, Ca, Sr, Ba) elements …

The development of catalysts for environmentally benign organic transformations is a very
active area of research. Most of the catalysts reported so far are based on transition-metal …

Here we present the first example of a single-site main group catalyst stabilized by a metal–
organic framework (MOF) for organic transformations. The straightforward metalation of the …

Utilization of main-group metals as alternatives to transition metals in homogeneous
catalysis has become a hot research area in recent years. However, their application in …

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

Metal complexes with heteroscorpionate ligands based on the bis(pyrazol-1-yl)methane
moiety: Catalytic chemistry - ScienceDirect Skip to main contentSkip to article Elsevier logo …

This Perspective article provides an overview of the recent advancements in the field of intra-
and inter-molecular C–N, C–O and C–P bond formation by hydroamination …

The addition of an N–H bond to an olefin is the most direct route for the synthesis of
alkylamines. Currently, intermolecular hydroamination is limited to reactions of a narrow …