Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Conspectus Atropisomers, arising from conformational restriction, are inherently chiral due
to the intersecting dissymmetric planes. Since there are numerous applications of …

Stereochemical enrichment of a racemic mixture by deracemization must overcome
unfavorable entropic effects as well as the principle of microscopic reversibility; recently …

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes | Chemical Reviews ACS
ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS Publications …

When faced with unfamiliar reaction space, synthetic chemists typically apply the reported
conditions (reagents, catalyst, solvent and additives) of a successful reaction to a desired …

The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Over the past few years, CuH‐catalyzed hydroamination has been discovered and
developed as a robust and conceptually novel approach for the synthesis of …

The nature of the excited state renders the development of chiral catalysts for
enantioselective photochemical reactions a considerable challenge. The absorption of a …

Asymmetric catalysis is seen as one of the most economical strategies to satisfy the growing
demand for enantiomerically pure small molecules in the fine chemical and pharmaceutical …

Axially chiral open‐chain olefins represent an underexplored class of chiral platform. In this
report, two classes of tetrasubstituted axially chiral acyclic olefins have been accessed in …