Tris (pyridyl) borates: an emergent class of versatile and robust polydentate ligands for catalysis and materials applications

J McQuade, F Jäkle - Dalton Transactions, 2023 - pubs.rsc.org
Tridentate ligands that incorporate pyridyl rather than pyrazolyl groups are emerging as an
attractive class of “scorpionate”-type ligands with enhanced electron donation, increased …

Design strategies, surface functionalization, and environmental remediation potentialities of polymer-functionalized nanocomposites

CH Yu, UM Betrehem, N Ali, F Ali, S Nawaz, M Sajid… - Chemosphere, 2022 - Elsevier
Inorganic nanoparticles (NPs) have a tunable shape, size, surface morphology, and unique
physical properties like catalytic, magnetic, electronic, and optical capabilities. Unlike …

Synthesis and Ring-Opening Metathesis Polymerization of a Strained trans-Silacycloheptene and Single-Molecule Mechanics of Its Polymer

H Wakefield IV, I Kevlishvili, KE Wentz… - Journal of the …, 2023 - ACS Publications
The cis-and trans-isomers of a silacycloheptene were selectively synthesized by the
alkylation of a silyl dianion, a novel approach to strained cycloalkenes. The trans …

Water-soluble polyphosphonate-based bottlebrush copolymers via aqueous ring-opening metathesis polymerization

DA Resendiz-Lara, S Azhdari, H Gojzewski… - Chemical …, 2023 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) is a versatile method for synthesizing
complex macromolecules from various functional monomers. In this work, we report the …

Main-Chain Carborane-Embedded Polyethylene

J Zhang, Z Meng, Y He, Z Luo, X Li, Y Sha - Macromolecules, 2024 - ACS Publications
Functionalization of polyethylene toward high-performance polymers with good thermal and
mechanical properties is a persistent challenge. Closo-carboranes, with a polyhedral …

Mechanochemical Synthesis of Ionic Polymers: Solid-State Ball-Milling Polymerization for Unrestricted Solubility Enabling Copolymerization of Immiscible Monomers

GS Lee, HS Lee, N Kim, HG Shin, YH Hwang… - …, 2024 - ACS Publications
This study demonstrates the facile synthesis of ionic polymers using a solid-state
mechanochemical ball milling method, which offers a straightforward, ecofriendly, and broad …

Bottlebrush polymers via ring-opening metathesis polymerization (ROMP): Synthesis, properties and applications

SR Rout, G Kenguva, S Mansuri, KR Manu… - European Polymer …, 2024 - Elsevier
Bottlebrush polymers (BBPs) are a class of branch or graft macromolecules with polymeric
side chains attached to linear backbone leading to cylindrical or worm like structures. Due to …

Residual Strain Development in Rapid Frontally Curing Polymers

Z Chen, B Koohbor, X Zhang, LM Dean… - ACS Applied …, 2024 - ACS Publications
Frontal polymerization (FP) has emerged as a rapid and energy-efficient process for
fabricating thermoset polymers and composites. In this process, a self-propagating reaction …

Synthesis of aminopyrazine‐based fire resistant additive and its application in epoxy resin

M Ma, Q Yang, T Meng, Y Wei, Y Pan… - … Engineering & Science, 2024 - Wiley Online Library
A new fire retardency APD was synthesized successfully by the condensation between 2‐
aminopyrazine and DOPO, and target product APD was characterized by NMR. Absorption …

Well-Tailored Norbornene-Based Fluorinated Copolymers toward Modulating Icephobicity and Mechanical Robustness

G Luo, Z Gao, C Zhou, Y Huang, S Hu, Y Hu, C Zong… - Langmuir, 2024 - ACS Publications
Well-tailored construction of icephobic surfaces with mechanical robustness and
investigation of the structure–property relationships at the molecular level are highly …