Although the first ylide appeared as early as the 1900s, the recognition of these structurally
interesting compounds as synthetically useful reagents was only realized after the birth of …

The reaction of sulfur ylides with carbonyl compounds to give epoxides is an important
synthetic method. This Account charts the recent advances in rendering this process both …

Nucleophilic Dearomatizing (DNAr) Reactions of Aromatic C,H-Systems. A Mature Paradigm in
Organic Synthesis | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log …

Rearrangement reactions occupy a special place within the canon of organic synthesis, by
virtue of the inherently high efficiency of chemical processes which form and break bonds by …

A variety of metalated tosylhydrazone salts derived from benzaldehyde have been prepared
and were reacted with benzaldehyde in the presence of tetrahydrothiophene (THT)(20 …

Benzotetramisole promotes the catalytic asymmetric [2, 3]-rearrangement of allylic
quaternary ammonium salts (either isolated or prepared in situ from p-nitrophenyl …

Conclusions The past decade has seen an increased appreciation for the synthetic utility of
the Stevens rearrangement. An important component of this growth has been the …

By a sidearm approach, camphor-derived sulfur ylides 1 were designed and synthesized for
the cyclopropanation of electron-deficient alkenes and epoxidation of aldehydes. Under the …

Water-soluble [RuII (4-Glc-TPP)(CO)](1, 4-Glc-TPP= meso-tetrakis (4-(β-d-glucosyl) phenyl)
porphyrinato dianion) is an active catalyst for the following carbenoid transfer reactions in …

The [1, 2]-Stevens rearrangement is a widely used transformation in synthetic organic
chemistry. However, enantioselective versions are relatively limited and most of them rely on …