Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
Hypervalent iodine reagents in the total synthesis of natural products
LF Silva Jr, B Olofsson - Natural product reports, 2011 - pubs.rsc.org
Covering: 2008–2010 This report describes the recent applications of hypervalent iodine
reagents in the total synthesis of natural products. The large diversity of high-yielding and …
reagents in the total synthesis of natural products. The large diversity of high-yielding and …
[图书][B] Progress in the chemistry of organic natural products
Termites (Isoptera), which are a suborder of the cockroaches, are the oldest eusocial insects
[1–3]. It is assumed that they diverged from the Cryptocercoidae, woodfeeding cockroaches …
[1–3]. It is assumed that they diverged from the Cryptocercoidae, woodfeeding cockroaches …
Development of a drug discovery approach from microbes with a special focus on isolation sources and taxonomy
Y Igarashi - The Journal of Antibiotics, 2023 - nature.com
After the successful discoveries of numerous antibiotics from microorganisms, frequent
reisolation of known compounds becomes an obstacle in further development of new drugs …
reisolation of known compounds becomes an obstacle in further development of new drugs …
The logic of translating chemical knowledge into machine-processable forms: a modern playground for physical-organic chemistry
K Molga, EP Gajewska, S Szymkuć… - Reaction Chemistry & …, 2019 - pubs.rsc.org
Recent years have brought renewed interest–and tremendous progress–in computer-
assisted synthetic planning. Although the vast majority of the proposed solutions rely on …
assisted synthetic planning. Although the vast majority of the proposed solutions rely on …
Total synthesis of (−)-marinisporolide C
LC Dias, EC de Lucca Jr - The Journal of Organic Chemistry, 2017 - ACS Publications
The first total synthesis of (−)-marinisporolide C is described, which establishes
unequivocally the relative and absolute configuration of this oxopolyene macrolide. Key …
unequivocally the relative and absolute configuration of this oxopolyene macrolide. Key …
Total synthesis of (−)-goniotrionin
LC Dias, MAB Ferreira - The Journal of Organic Chemistry, 2012 - ACS Publications
A stereoselective total synthesis of the reported structure of goniotrionin (4) has been
accomplished. The key steps involved the opening of a chiral epoxide, a highly …
accomplished. The key steps involved the opening of a chiral epoxide, a highly …
Total synthesis of pteridic acid A
JS Yadav, V Rajender, YG Rao - Organic Letters, 2010 - ACS Publications
A convergent approach to the total synthesis of pteridic acid A, having potent plant growth
regulator activity, is described. Key steps include the desymmetrization of bicyclic olefin with …
regulator activity, is described. Key steps include the desymmetrization of bicyclic olefin with …
Facile preparation and reactivity of bifunctional ionic liquid-supported hypervalent iodine reagent: a convenient recyclable reagent for catalytic oxidation
Novel, efficient, and recyclable bifunctional catalysts bearing ionic liquid supported (2, 2, 6, 6-
tetramethylpiperidin-1-yl) oxyl (TEMPO) and iodoarene moieties were developed and used …
tetramethylpiperidin-1-yl) oxyl (TEMPO) and iodoarene moieties were developed and used …
Nhatrangin A: Total syntheses of the proposed structure and six of its diastereoisomers
LC Dias, EC Polo - The Journal of Organic Chemistry, 2017 - ACS Publications
A total synthesis of the proposed structure of nhatrangin A is described. This strategy relies
on two aldol reactions to install the chiral centers at C3/C4 and C3′/C4′, a lithium …
on two aldol reactions to install the chiral centers at C3/C4 and C3′/C4′, a lithium …