Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities

C Wu, N Corrigan, CH Lim, W Liu, G Miyake… - Chemical …, 2022 - ACS Publications
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …

PET-RAFT polymerization: Mechanistic perspectives for future materials

ML Allegrezza, D Konkolewicz - ACS Macro Letters, 2021 - ACS Publications
In the past decade, photochemistry has emerged as a growing area in organic and polymer
chemistry. Use of light to drive polymerization has advantages by imparting spatial and …

PET-RAFT polymerisation: towards green and precision polymer manufacturing

J Phommalysack-Lovan, Y Chu, C Boyer… - Chemical …, 2018 - pubs.rsc.org
The necessity of sustainable development in the chemical industry has continuously drawn
attention to find safe, environmentally friendly and atom-economic chemical processes …

Oxygen tolerance in living radical polymerization: investigation of mechanism and implementation in continuous flow polymerization

N Corrigan, D Rosli, JWJ Jones, J Xu, C Boyer - Macromolecules, 2016 - ACS Publications
The production of a range of acrylate and acrylamide polymers in completely open reaction
vessels has been achieved utilizing the PET-RAFT polymerization technique with zinc …

Photocontrolled living polymerization systems with reversible deactivations through electron and energy transfer

S Shanmugam, J Xu, C Boyer - Macromolecular Rapid …, 2017 - Wiley Online Library
Recently, visible‐light‐regulated polymerization has been gaining popularity, as it opens a
range of new opportunities for the synthesis of functional polymers and materials. Here, the …

Recent advances in RAFT polymerization: Novel initiation mechanisms and optoelectronic applications

X Tian, J Ding, B Zhang, F Qiu, X Zhuang, Y Chen - Polymers, 2018 - mdpi.com
Reversible addition-fragmentation chain transfer (RAFT) is considered to be one of most
famous reversible deactivation radical polymerization protocols. Benefiting from its living or …

Organic Photocatalyst for ppm-Level Visible-Light-Driven Reversible Addition–Fragmentation Chain-Transfer (RAFT) Polymerization with Excellent Oxygen Tolerance

Y Song, Y Kim, Y Noh, VK Singh, SK Behera… - …, 2019 - ACS Publications
A highly efficient organic photocatalyst (OPC) for photoinduced electron/energy-transfer
reversible addition–fragmentation chain-transfer (PET-RAFT) polymerization was identified …

Solar-Driven Lignin Oxidation via Hydrogen Atom Transfer with a Dye-Sensitized TiO2 Photoanode

S Li, ZJ Li, H Yu, MR Sytu, Y Wang, D Beeri… - ACS energy …, 2019 - ACS Publications
Molecular-based dye-sensitized photoelectrochemical cells (DSPECs) have traditionally
targeted solar-driven water splitting for the conversion of solar energy into fuels in aqueous …

Electrochemically mediated reversible addition–fragmentation chain-transfer polymerization

Y Wang, M Fantin, S Park, E Gottlieb, L Fu… - …, 2017 - ACS Publications
An electrochemically mediated reversible addition–fragmentation chain-transfer
polymerization (e RAFT) of (meth) acrylates was successfully carried out via electroreduction …