Covalent organic frameworks

KT Tan, S Ghosh, Z Wang, F Wen… - Nature Reviews …, 2023 - nature.com
The dream to prepare well-defined materials drives the methodological evolution for
molecular synthesis, structural control and materials manufacturing. Among various …

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Landscaping covalent organic framework nanomorphologies

HS Sasmal, A Kumar Mahato, P Majumder… - Journal of the …, 2022 - ACS Publications
The practical utilization of covalent organic frameworks (COFs) with manipulation at the
atomic and molecular scale often demands their assembly on the nano-, meso-, and …

Single-crystalline imine-linked two-dimensional covalent organic frameworks separate benzene and cyclohexane efficiently

A Natraj, W Ji, J Xin, I Castano, DW Burke… - Journal of the …, 2022 - ACS Publications
Two-dimensional (2D) covalent organic frameworks (COFs) are composed of structurally
precise, permanently porous, layered macromolecular sheets, which are traditionally …

Constitutional isomerism of the linkages in donor–acceptor covalent organic frameworks and its impact on photocatalysis

J Yang, S Ghosh, J Roeser, A Acharjya… - Nature …, 2022 - nature.com
When new covalent organic frameworks (COFs) are designed, the main efforts are typically
focused on selecting specific building blocks with certain geometries and properties to …

Growth of single-crystal imine-linked covalent organic frameworks using amphiphilic amino-acid derivatives in water

Z Zhou, L Zhang, Y Yang, IJ Vitorica-Yrezabal… - Nature Chemistry, 2023 - nature.com
A core feature of covalent organic frameworks (COFs) is crystallinity, but current
crystallization processes rely substantially on trial and error, chemical intuition and large …

2D conjugated covalent organic frameworks: defined synthesis and tailor-made functions

T Zhang, G Zhang, L Chen - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Covalent organic frameworks (COFs) are an emerging class of crystalline
porous polymers and have received tremendous attention and research interest. COFs can …

Porous materials for capture and catalytic conversion of CO2 at low concentration

M Ding, X Liu, P Ma, J Yao - Coordination Chemistry Reviews, 2022 - Elsevier
Carbon accumulation has raised worldwide concerns due to the risks of climate change. In
such cases, direct carbon dioxide (CO 2) capture and conversion from diluted sources has …

Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study

C Kang, K Yang, Z Zhang, AK Usadi… - Nature …, 2022 - nature.com
Resolving single-crystal structures of two-dimensional covalent organic frameworks (2D
COFs) is a great challenge, hindered in part by limited strategies for growing high-quality …

Tuning crystallinity and stacking of two-dimensional covalent organic frameworks through side-chain interactions

CE Pelkowski, A Natraj, CD Malliakas… - Journal of the …, 2023 - ACS Publications
Two-dimensional covalent organic frameworks (2D COFs) form as layered 2D polymers
whose sheets stack through high-surface-area, noncovalent interactions that can give rise to …