Multiplicity of metal ion binding patterns to nucleobases

B Lippert - Coordination Chemistry Reviews, 2000 - Elsevier
The systematic study of interactions between metal ions and nucleobases, the constituents
of nucleic acids, as well as nucleic acids in general started some 50 years ago, around …

Electronic properties, hydrogen bonding, stacking, and cation binding of DNA and RNA bases

J Šponer, J Leszczynski… - … : Original Research on …, 2001 - Wiley Online Library
This review summarizes results concerning molecular interactions of nucleic acid bases as
revealed by advanced ab initio quantum chemical (QM) calculations published in last few …

Nucleic acid duplexes with metal-mediated base pairs and their structures

J Müller - Coordination Chemistry Reviews, 2019 - Elsevier
Metal-mediated base pairs represent a topical area of research at the border of bioinorganic
chemistry, supramolecular coordination chemistry and DNA nanotechnology. In a metal …

Prototropic tautomerism of heterocycles: heteroaromatic tautomerism—general overview and methodology

J Elguero, AR Katritzky, OV Denisko - Advances in Heterocyclic Chemistry, 2000 - Elsevier
In 1963 one of us, together with JM Lagowski, published in Volumes 1 and 2 of Advances in
Heterocyclic Chemistry four chapters [63AHC (1), p. 312, p. 341; 63AHC (2), p. 3, p. 28] …

Impact of Cisplatin on the recent development of Pt coordination chemistry: a case study

B Lippert - Coordination chemistry reviews, 1999 - Elsevier
An overview is presented on recent developments in selected areas of Pt coordination
chemistry which were a direct consequence of the discovery of the antitumor activity of cis-Pt …

The renaissance of metal–pyrimidine nucleobase coordination chemistry

B Lippert, PJ Sanz Miguel - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus The significance of metal ions for the function and properties of DNA and RNA,
long seen primarily under biological aspects and medicinal uses, has recently gained a …

Functional metal ions in nucleic acids

J Müller - Metallomics, 2010 - academic.oup.com
Metal ions are inevitably involved in almost every aspect of nucleic acid chemistry. Their
most prominent role is certainly the maintenance of nucleic acid structural integrity …

Alterations of Nucleobase pK a Values upon Metal Coordination: Origins and Consequences

B Lippert - Progress in Inorganic Chemistry, 2005 - Wiley Online Library
In nucleic acids, the nucleobases are typically uncharged in the physiological range 4< pH<
9. Like any other chemical modification of a nucleobase, metal coordination perturbs the …

Metal-stabilized rare tautomers and mispairs of DNA bases: N6-metalated adenine and N4-metalated cytosine, theoretical and experimental views

J Šponer, JE Šponer, L Gorb… - The Journal of …, 1999 - ACS Publications
Crystal structure studies indicate that metalation of the exocyclic amino group of cytosine
and adenine nucleobases by PtII and HgII entities, respectively, induces protonation of a …

More of a misunderstanding than a real mismatch? Platinum and its affinity for aqua, hydroxido, and oxido ligands

B Lippert, PJS Miguel - Coordination Chemistry Reviews, 2016 - Elsevier
This article reviews discrete complexes of platinum in its common oxidation states+ II,+ III,
and+ IV with aqua, hydroxido, oxido, and peroxido ligands, which at some point had been …