[HTML][HTML] Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance

IE Khalil, J Fonseca, MR Reithofer, T Eder… - Coordination Chemistry …, 2023 - Elsevier
As the structure and properties of anisotropic metal–organic frameworks (MOFs) vary with
certain directions in space, controlling the orientation of these MOFs allows full advantage to …

Assembling metal–organic cages as porous materials

E Sánchez-González, MY Tsang, J Troyano… - Chemical Society …, 2022 - pubs.rsc.org
There is growing interest in metal–organic cages (MOCs) as porous materials owing to their
processability in solution. The discrete molecular character and surface features of MOCs …

MOF‐on‐MOF architectures: applications in separation, catalysis, and sensing

DH Hong, HS Shim, J Ha… - Bulletin of the Korean …, 2021 - Wiley Online Library
Metal–organic frameworks (MOFs) are porous crystalline materials with a high tunability. To
improve the functionality of the original frameworks, several strategies, such as the use of …

Coordination/metal–organic cages inside out

T Tateishi, M Yoshimura, S Tokuda, F Matsuda… - Coordination Chemistry …, 2022 - Elsevier
Cage-like molecules, assembled by the coordination of multiple metal ions and organic
links, are pushing new frontiers in science due to their design flexibility and the resulting …

Catalytically active sites of MOF-derived electrocatalysts: synthesis, characterization, theoretical calculations, and functional mechanisms

Z Zhai, W Yan, L Dong, S Deng, DP Wilkinson… - Journal of Materials …, 2021 - pubs.rsc.org
Electrocatalysts play critical roles in electrochemical energy storage and conversion
technologies such as fuel cells, metal–air batteries, and H2O/CO2/N2 electrolysis. Recently …

Benzimidazole-based covalent organic framework embedding single-atom Pt sites for visible-light-driven photocatalytic hydrogen evolution

F Ma, Q Tang, S Xi, G Li, T Chen, X Ling, Y Lyu… - Chinese Journal of …, 2023 - Elsevier
Visible-light-driven photocatalytic hydrogen evolution reaction (HER) over a semiconductor
provides an effective avenue to produce renewable clean energy and alleviate energy and …

Cooperativity of steric bulk and H-bonding in coordination sphere engineering: heteroleptic Pd II cages and bowls by design

B Chen, JJ Holstein, A Platzek, L Schneider, K Wu… - Chemical …, 2022 - pubs.rsc.org
Recently developed self-assembly strategies allow to rationally reduce the symmetry of
metallosupramolecular architectures. In addition, the combination of multiple ligand types …

Synthesis of MOF-on-MOF architectures in the context of interfacial lattice matching

J Ha, HR Moon - CrystEngComm, 2021 - pubs.rsc.org
Functional materials based on metal–organic frameworks (MOFs), especially MOF-on-MOF
architectures, have attracted great interest for their potential application in a range of fields …

Resistive memory devices based on reticular materials for electrical information storage

J Oh, SM Yoon - ACS Applied Materials & Interfaces, 2021 - ACS Publications
Recently, reticular materials, such as metal–organic frameworks and covalent organic
frameworks, have been proposed as an active insulating layer in resistive switching memory …

A New Era of Modeling MOF‐Based Membranes: Cooperation of Theory and Data Science

H Demir, S Keskin - Macromolecular Materials and Engineering, 2024 - Wiley Online Library
Membrane‐based separation can offer significant energy savings over conventional
separation methods. Given their highly customizable and porous structures, metal–organic …