Progress in design and applications of supramolecular assembly of 2, 2′: 6′, 2 ″-terpyridine-based first row d-block elements

BZ Momeni, N Davarzani, J Janczak, N Ma… - Coordination Chemistry …, 2024 - Elsevier
Abstract 2, 2′: 6′, 2 ″-Terpyridine (tpy)-based transition metal complexes have continued
to receive attention due to their outstanding features and promising industrial and …

Cancer phototherapy by CO releasing terpyridine-based Re (i) tricarbonyl complexes via ROS generation and NADH oxidation

R Kushwaha, A Upadhyay, S Saha, AK Yadav… - Dalton …, 2024 - pubs.rsc.org
Here, we have synthesized and characterized three visible light responsive terpyridine
based-Re (I)-tricarbonyl complexes;[Re (CO) 3 (ph-tpy) Cl](Retp1),[Re (CO) 3 (an-tpy) …

Push-pull effect–how to effectively control photoinduced intramolecular charge transfer processes in rhenium (I) chromophores with ligands of D–A or D–π–A structure

K Choroba, J Palion-Gazda, A Kryczka, E Malicka… - Dalton …, 2025 - pubs.rsc.org
Over the last five decades, diimine rhenium (I) tricarbonyl complexes have been extensively
investigated due to their remarkable and widely tuned photophysical properties. These …

The Role of Intraligand Charge Transfer Processes in Iridium (III) Complexes with Morpholine-Decorated 4′-Phenyl-2, 2′: 6′, 2 ″-terpyridine

J Palion-Gazda, A Kwiecień, K Choroba, M Penkala… - Molecules, 2024 - mdpi.com
To investigate the impact of the electron-donating morpholinyl (morph) group on the ground-
and excited-state properties of two different types of Ir (III) complexes,[IrCl3 (R-C6H4-terpy …

Effect of the Appended Morpholinyl Group on Photophysical Behavior of Mono-and Bis-cyclometalated Terpyridine Iridium (III) Chromophores

J Palion-Gazda, A Kwiecień, K Choroba… - Inorganic …, 2025 - ACS Publications
This paper provides extensive studies of [IrCl (Ph-py)(morph-C6H4-terpy-κ3N)] PF6 (1A),[Ir
(Ph-py) 2 (morph-C6H4-terpy-κ2N)] PF6 (2A),[IrCl (Ph-py)(Ph-terpy-κ3N)] PF6 (1B), and [Ir …

Synthesis, characterization and photophysical properties of rhenium (I) tricarbonyl complexes with thiacrown ethers

RA Odhiambo, LW Njenga - Inorganica Chimica Acta, 2024 - Elsevier
Crown ethers and their derivatives are known to coordinate metal cations and organic
molecules. They have an adaptable ring-opening diameter, which makes their …

Electrocatalytic reduction of CO 2 to CO by a series of organometallic Re (i)-tpy complexes

S Saha, T Doughty, D Banerjee, SK Patel… - Dalton …, 2023 - pubs.rsc.org
A series of organometallic Re (I)(L)(CO) 3Br complexes with 4′-substituted terpyridine
ligands (L) has been synthesised as electrocatalysts for CO2 reduction. The complexes' …

Structural and Photophysical Trends in Rhenium (I) Carbonyl Complexes with 2, 2′: 6′, 2 ″-Terpyridines

J Palion-Gazda, K Choroba, AM Maroń, E Malicka… - Molecules, 2024 - mdpi.com
This is the first comprehensive review of rhenium (I) carbonyl complexes with 2, 2′: 6′, 2
″-terpyridine-based ligands (R-terpy)—encompassing their synthesis, molecular features …

Organophosphonic acid catalyzed dehydrogenative coupling of hydrosilanes with alcohols under solvent-free conditions

Z Han, M Chai, Y Bai, W Huang… - Main Group Metal …, 2024 - degruyter.com
There is a strong need for exploring the new preparation methods for silyl ethers due to their
great potential in synthetic chemistry and materials. At present, the catalytic dehydrogenative …

Photophysics of transition metal complexes (2021–2022)

S La Cognata, D Vadivel, A Poggi, D Dondi… - 2023 - books.rsc.org
This Chapter summarizes the major advances in the photophysics of transition metal
complexes, achieved in 2021 and 2022, covering mainly d-block metal complexes. The …