Switchable polymerization catalysts

AJ Teator, DN Lastovickova, CW Bielawski - Chemical reviews, 2016 - ACS Publications
The intrinsic physical properties and functionalities displayed by synthetic polymers are
directly correlated to their respective microstructures. For example, complex biopolymers …

Water in N-heterocyclic carbene-assisted catalysis

E Levin, E Ivry, CE Diesendruck, NG Lemcoff - Chemical reviews, 2015 - ACS Publications
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …

Plasmonic visible–near infrared photothermal activation of olefin metathesis enabling photoresponsive materials

N Lemcoff, NB Nechmad, O Eivgi, E Yehezkel… - Nature Chemistry, 2023 - nature.com
Light-induced catalysis and thermoplasmonics are promising fields creating many
opportunities for innovative research. Recent advances in light-induced olefin metathesis …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Deep red to near-infrared light-controlled ruthenium-catalyzed olefin metathesis

DC Cabanero, JA Nguyen, CSJ Cazin, SP Nolan… - ACS …, 2023 - ACS Publications
A system has been developed to activate a latent ruthenium olefin metathesis catalyst using
deep red to near-infrared light (600–800 nm) in conjunction with an osmium (II) …

Photocatalysts in polymerization reactions

N Zivic, M Bouzrati‐Zerelli, A Kermagoret… - …, 2016 - Wiley Online Library
A short review of the role of photocatalysts in photopolymerization reactions is presented. A
special emphasis is placed on photoredox catalysts leading to i) high‐performance initiating …

Light-activated olefin metathesis: catalyst development, synthesis, and applications

O Eivgi, RS Phatake, NB Nechmad… - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The most important means for tuning and improving a catalyst's properties is the
delicate exchange of the ligand shell around the central metal atom. Perhaps for no other …

Visible-light-controlled ruthenium-catalyzed olefin metathesis

C Theunissen, MA Ashley, T Rovis - Journal of the American …, 2019 - ACS Publications
Olefin metathesis is now one of the most efficient ways to create new carbon–carbon bonds.
While most efforts focused on the development of ever-more efficient catalysts, a particular …

Spatial and temporal control of chemical processes

S Aubert, M Bezagu, AC Spivey… - Nature Reviews …, 2019 - nature.com
Controlling the where and when of a chemical reaction, rather than just the if, can be an
essential component in the successful development of applications. There are a large …

Homogeneous photocatalytic reactions with organometallic and coordination compounds—Perspectives for sustainable chemistry

N Hoffmann - ChemSusChem, 2012 - Wiley Online Library
Since the time of Giacomo Ciamician at the beginning of the 20th century, photochemical
transformations have been recognized as contributing to sustainable chemistry. Electronic …