Water oxidation catalysts for artificial photosynthesis

S Ye, C Ding, M Liu, A Wang, Q Huang… - Advanced …, 2019 - Wiley Online Library
Water oxidation is the primary reaction of both natural and artificial photosynthesis.
Developing active and robust water oxidation catalysts (WOCs) is the key to constructing …

Molecular and heterogeneous water oxidation catalysts: recent progress and joint perspectives

J Li, CA Triana, W Wan, DPA Saseendran… - Chemical Society …, 2021 - pubs.rsc.org
The development of reliable water oxidation catalysts (WOCs) is essential for implementing
artificial photosynthesis on a large technological scale. WOC research has evolved into two …

Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges

MD Kärkäs, B Åkermark - Dalton Transactions, 2016 - pubs.rsc.org
Catalysts for the oxidation of H2O are an integral component of solar energy to fuel
conversion technologies. Although catalysts based on scarce and precious metals have …

Electrocatalytic water oxidation by a copper (II) complex of an oxidation-resistant ligand

KJ Fisher, KL Materna, BQ Mercado, RH Crabtree… - ACS …, 2017 - ACS Publications
The copper (II) complex Cu (pyalk) 2 (pyalk= 2-pyridyl-2-propanoate) is a robust
homogeneous water-oxidation electrocatalyst under basic conditions (pH> 10.4). Water …

Copper-based homogeneous and heterogeneous catalysts for electrochemical water oxidation

H Lee, X Wu, L Sun - Nanoscale, 2020 - pubs.rsc.org
Water oxidation is currently believed to be the bottleneck in the field of electrochemical water
splitting and artificial photosynthesis. Enormous efforts have been devoted toward the …

Structure/property control in photocatalytic organic semiconductor nanocrystals

Y Chen, C Yan, J Dong, W Zhou… - Advanced Functional …, 2021 - Wiley Online Library
Photocatalysis offers a practical solution to the ever increasing energy and environmental
issues by using a semiconductor to harvest freely available sunlight. Photoactive organic …

Electrocatalytic water oxidation by a homogeneous copper catalyst disfavors single-site mechanisms

SJ Koepke, KM Light, PE VanNatta… - Journal of the …, 2017 - ACS Publications
Deployment of solar fuels derived from water requires robust oxygen-evolving catalysts
made from earth abundant materials. Copper has recently received much attention in this …

A Bio‐inspired Cu4O4 Cubane: Effective Molecular Catalysts for Electrocatalytic Water Oxidation in Aqueous Solution

X Jiang, J Li, B Yang, XZ Wei, BW Dong… - Angewandte …, 2018 - Wiley Online Library
Inspired by the cubic Mn4CaO5 cluster of natural oxygen‐evolving complex in Photosystem
II, tetrametallic molecular water oxidation catalysts, especially M4O4 cubane‐like clusters …

Bioinspired molecular clusters for water oxidation

QF Chen, YH Guo, YH Yu, MT Zhang - Coordination Chemistry Reviews, 2021 - Elsevier
Abstract Water oxidation (2 H 2 O→ 4H++ 4 e-+ O 2) is a key step in utilization of solar
energy for producing hydrogen of artificial photosynthetic system. Inspired by the oxygen …

Unusual water oxidation mechanism via a redox-active copper polypyridyl complex

D den Boer, AI Konovalov, MA Siegler… - Inorganic …, 2023 - ACS Publications
To improve Cu-based water oxidation (WO) catalysts, a proper mechanistic understanding of
these systems is required. In contrast to other metals, high-oxidation-state metal–oxo …