Melanin biopolymers: Tailoring chemical complexity for materials design

M d'Ischia, A Napolitano, A Pezzella… - Angewandte Chemie …, 2020 - Wiley Online Library
Melanins, a group of dark insoluble pigments found widespread in nature, have become the
focus of growing interest in materials science for various biomedical and technological …

[HTML][HTML] Bio-applications of multifunctional melanin nanoparticles: from nanomedicine to nanocosmetics

A Mavridi-Printezi, M Guernelli, A Menichetti, M Montalti - Nanomaterials, 2020 - mdpi.com
Bioinspired nanomaterials are ideal components for nanomedicine, by virtue of their
expected biocompatibility or even complete lack of toxicity. Natural and artificial melanin …

Disentangling the Puzzling Regiochemistry of Thiol Addition to o-Quinones

ML Alfieri, A Cariola, L Panzella… - The Journal of …, 2022 - ACS Publications
The addition of thiol compounds to o-quinones, as exemplified by the biologically relevant
conjugation of cysteine to dopaquinone, displays an anomalous 1, 6-type regiochemistry …

[HTML][HTML] Thiol-yne click reaction: An interesting way to derive thiol-provided catechols

F Nador, J Mancebo-Aracil, D Zanotto, D Ruiz-Molina… - RSC …, 2021 - pubs.rsc.org
The hydrothiolation of activated alkynes is presented as an attractive and powerful way to
functionalize thiols bearing catechols. The reaction was promoted by a heterogeneous …

Total Synthesis of Racemic Thieno[3,2-f]thiochromene Tricarboxylate, a Luciferin from Marine Polychaeta Odontosyllis undecimdonta

YV Bolt, MA Dubinnyi, VV Litvinenko, AA Kotlobay… - Organic …, 2023 - ACS Publications
We report the first total synthesis of racemic Odontosyllis undecimdonta luciferin, a thieno [3,
2-f] thiochromene tricarboxylate comprising a 6-6-5-fused tricyclic skeleton with three sulfur …

[HTML][HTML] Functionalization of and through Melanin: Strategies and Bio-Applications

A Mavridi-Printezi, A Menichetti, D Mordini… - International Journal of …, 2023 - mdpi.com
A unique feature of nanoparticles for bio-application is the ease of achieving multi-
functionality through covalent and non-covalent functionalization. In this way, multiple …

[HTML][HTML] Mussel-Inspired Lego Approach for Controlling the Wettability of Surfaces with Colorless Coatings

C Casagualda, J Mancebo-Aracil, M Moreno-Villaécija… - Biomimetics, 2022 - mdpi.com
The control of surface wettability with polyphenol coatings has been at the forefront of
materials research since the late 1990s, when robust underwater adhesion was linked to the …

A Bioinspired Synthesis of 1,4-Benzothiazines by Selective Addition of Sulfur Nucleophiles to ortho-Quinones

MW Halloran, E Li, KVN Esguerra… - The Journal of Organic …, 2023 - ACS Publications
Herein, we report a bioinspired approach to the synthesis of 1, 4-benzothiazines by drawing
inspiration from the biosynthesis of pheomelanin pigments (pheomelanogenesis). In this …

Oxidative Dehydroxycyclization of Catechols with o-Mercaptoanilines to Access 1-Hydroxyphenothiazines

H Zhou, X Shang, W Li, C Zhu, G Yang… - The Journal of Organic …, 2024 - ACS Publications
The protocol of aerobic oxidative dehydroxycyclization installed in the synthesis of rarely
studied 1-hydroxyphenothiazines from catechols and o-mercaptoanilines is presented …

[HTML][HTML] Synthesis and antioxidant activity of new catechol thioethers with the methylene linker

IV Smolyaninov, DA Burmistrova, MV Arsenyev… - Molecules, 2022 - mdpi.com
Novel catechol thio-ethers with different heterocyclic substituents at sulfur atom were
prepared by reacting 3, 5-di-tert-butyl-6-methoxymethylcatechol with functionalized thiols …