Palladium-catalyzed selective five-fold cascade arylation of the 12-vertex monocarborane anion by B–H activation

F Lin, JL Yu, Y Shen, SQ Zhang… - Journal of the …, 2018 - ACS Publications
A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed
intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …

Palladium catalyzed selective arylation of o-carboranes via B (4)–H activation: amide induced regioselectivity reversal

TT Xu, K Cao, CY Zhang, J Wu, L Jiang… - Chemical …, 2018 - pubs.rsc.org
By changing the charge distribution of boron vertices via introducing an amide on cage B
(9), the selective B (4) arylation of o-carboranes via Suzuki–Miyaura coupling has been …

Catalytic Oxidative Dehydrogenative Coupling of Cage B–H/B–H Bonds for Synthesis of Bis(o-carborane)s

J Wu, K Cao, CY Zhang, TT Xu, LF Ding, B Li… - Organic letters, 2019 - ACS Publications
An efficient and succinct protocol for synthesis of bis (o-carborane) connected by a B–B
bond via palladium catalyzed oxidative dehydrogenative coupling of cage B–H/B–H bonds …

Low internal reorganization energy of the metal–metal-to-ligand charge transfer emission in dimeric Pt (II) complexes

WC Chen, PT Chou, YC Cheng - The Journal of Physical …, 2019 - ACS Publications
To achieve near-infrared (NIR) emitters with high photoluminescence quantum yield,
reduction of nonradiative decay is necessary. There, the energy gap law dictates that as the …

Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes

Y Shen, K Zhang, X Liang, R Dontha, S Duttwyler - Chemical Science, 2019 - pubs.rsc.org
Palladium-catalyzed dehydrogenative B–H/C–H cross coupling of monocarborane anions
with alkenes is reported, allowing for the first time the isolation of selectively penta …

Computational studies on the materials combining graphene quantum dots and Pt complexes with adjustable luminescence characteristics

SP Wang, Y Li, ZX Zhang, Y Zhang, Y Wang… - Inorganic …, 2021 - ACS Publications
Graphene materials with particular properties are proved to be beneficial to photoelectric
devices, but there are rare reports on a positive effect by graphene on emissive layer …

Enhancing quantum efficiency in Pt-based emitters using a pendant closo-monocarborane cluster to enforce charge neutrality

R Yang, Y Zhou, H Bian, G Cheng, Y Zhang… - Chemical Engineering …, 2022 - Elsevier
The use of organometallic triplet emitters in OLED applications may be complicated when
the luminescent complex bears a formal charge. By designing ligands containing pendant …

A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes

CY Zhang, K Cao, TT Xu, J Wu, L Jiang… - Chemical …, 2019 - pubs.rsc.org
A one pot deboronation/cyclization of 9-amide-o-carboranes for the synthesis of nido-7, 8-
carborane fused oxazole by cooperation of Pd (OAc) 2, AgOAc and K2CO3 has been …

Theoretical study of blue‐green iridium (III) complexes with low‐efficiency roll‐off properties for application in phosphorescent organic light‐emitting diodes

HY Chi, Y Ji, YK Zhang, XM Zhao, SJ Qu… - Applied …, 2024 - Wiley Online Library
To find an array of suitable materials for phosphorescent organic light‐emitting diodes
(OLEDs), in this paper, we design six blue‐green phosphorescent Ir (III) complexes that …

Palladium catalyzed/counter ion tuned selective methylation of o-carboranes

K Cao, CY Zhang, TT Xu, J Wu, LF Ding, L Jiang… - Journal of …, 2019 - Elsevier
The palladium catalyzed/counter ion tuned selective methylation of 9-amide-o-carboranes
on B (4) and B (12) has been developed, and a series of o-carborane derivatives decorated …