Copper–oxygen adducts: new trends in characterization and properties towards C–H activation
J De Tovar, R Leblay, Y Wang, L Wojcik… - Chemical …, 2024 - pubs.rsc.org
This review summarizes the latest discoveries in the field of C–H activation by copper
monoxygenases and more particularly by their bioinspired systems. This work first describes …
monoxygenases and more particularly by their bioinspired systems. This work first describes …
Toward three-dimensionally ordered nanoporous graphene materials: template synthesis, structure, and applications
M Yamamoto, S Goto, R Tang, K Yamazaki - Chemical Science, 2024 - pubs.rsc.org
Precise template synthesis will realize three-dimensionally ordered nanoporous graphenes
(NPGs) with a spatially controlled seamless graphene structure and fewer edges. These …
(NPGs) with a spatially controlled seamless graphene structure and fewer edges. These …
Revealing Active Sites and Reaction Pathways in Direct Oxidation of Methane over Fe-Containing CHA Zeolites Affected by the Al Arrangement
Fe-containing zeolites are effective catalysts in converting the greenhouse gases CH4 and
N2O into valuable chemicals. However, the activities of Fe-containing zeolites in methane …
N2O into valuable chemicals. However, the activities of Fe-containing zeolites in methane …
Roles of Acidic Proton for Fe-Containing Zeolite in Direct Oxidation of Methane
P Xiao, H Toyoda, Y Wang, K Nakamura, S Bekhti… - ACS …, 2024 - ACS Publications
Fe-containing zeolite catalysts are active in N2O decomposition and direct oxidation of
unreactive methane. Except for the well-known ability that acid sites realize the subsequent …
unreactive methane. Except for the well-known ability that acid sites realize the subsequent …
Zeolite-based catalysts for oxidative upgrading of methane: design and control of active sites
Oxidative upgrading of methane into carbon monoxide, methanol, lower hydrocarbons (such
as ethane and ethylene), and other oxygenates has been achieved at relatively low …
as ethane and ethylene), and other oxygenates has been achieved at relatively low …
Understanding the effect of spatially separated Cu and acid sites in zeolite catalysts on oxidation of methane
Unraveling the effect of spatially separated bifunctional sites on catalytic reactions is
significant yet challenging. In this report, we investigate the role of spatial separation on the …
significant yet challenging. In this report, we investigate the role of spatial separation on the …
Theoretical investigation on the structure-activity relationship for methane activation in Cu-CHA zeolite
The active sites and structure–activity relationship for methane activation over Cu-CHA were
investigated by Density Functional Theory (DFT) calculations.[CuOCu] 2+,[CuO 2 Cu] …
investigated by Density Functional Theory (DFT) calculations.[CuOCu] 2+,[CuO 2 Cu] …
Reactivity of Methoxy species towards Methylation and Oligomerization in Cu-Zeolite systems
Ethylene, propylene, and benzene were investigated as molecules for extracting methoxy
intermediate species formed during the cyclic partial oxidation of methane in Cu-exchanged …
intermediate species formed during the cyclic partial oxidation of methane in Cu-exchanged …
Tailoring Nanochannel in ZSM-5 Membranes via Al Distribution Control
M Sakai, S Moriya, R Matsumoto, T Kondo… - ACS Applied Nano …, 2024 - ACS Publications
The effects of Al distribution on the permeation and separation properties of the ZSM-5
membranes were investigated. Two types of ZSM-5 membranes with different Al distributions …
membranes were investigated. Two types of ZSM-5 membranes with different Al distributions …
Mechanistic Studies of Continuous Partial Methane Oxidation on Cu− Zeolites Using Kinetic and Spectroscopic Methods
Over the past few decades, a significant amount of research effort has focused on
investigating the active site requirements and reaction mechanisms for partial methane …
investigating the active site requirements and reaction mechanisms for partial methane …