SOD mimics: From the tool box of the chemists to cellular studies

C Policar, J Bouvet, HC Bertrand, N Delsuc - Current Opinion in Chemical …, 2022 - Elsevier
Superoxide dismutases (SODs) are metalloproteins that protect cells against oxidative stress
by controlling the concentration of superoxide (O 2−) through catalysis of its dismutation. The …

Transition metal complexes with tetradentate Schiff bases (N2O2) obtained from salicylaldehyde: A review of their possible anticancer properties

LA Alfonso-Herrera, D Hernández-Romero… - Coordination Chemistry …, 2024 - Elsevier
Despite multiple advances in prevention and treatment, cancer remains a deadly disease
globally. From 1942 to the present day, chemotherapy has been recognized as one of the …

Synthesis and characterization of two new mixed‐ligand Cu (II) complexes of a tridentate NN'O type Schiff base ligand and N‐donor heterocyclic co‐ligands: In vitro …

L Ghasemi, M Behzad, A Khaleghian… - Applied …, 2022 - Wiley Online Library
Two new mixed‐ligand complexes with general formula [Cu (SB)(L')] ClO4 (1 and 2) were
synthesized and characterized by different spectroscopic and analytical techniques …

Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese …

L Senft, JL Moore, A Franke, KR Fisher, A Scheitler… - Chemical …, 2021 - pubs.rsc.org
Reactivity assays previously suggested that two quinol-containing MRI contrast agent
sensors for H2O2,[Mn (H2qp1)(MeCN)] 2+ and [Mn (H4qp2) Br2], could also catalytically …

Fine‐Tuning Redox Properties of Heteroleptic Molybdenum Complexes through Ligand‐Ligand‐Cooperativity

BJ Elvers, S Pätsch, SSM Bandaru… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Heteroleptic molybdenum complexes bearing 1, 5‐diaza‐3, 7‐
diphosphacyclooctane (P2N2) and non‐innocent dithiolene ligands were synthesized and …

The Critical Role of Ligand Flexibility on the Activity of Free and Immobilized Mn Superoxide Dismutase Mimics

M Richezzi, S Signorella, C Palopoli, N Pellegri… - Inorganics, 2023 - mdpi.com
In low-molecular-weight Mn superoxide dismutase (SOD) mimics, the ligand plays a key role
in tuning the reactivity of the metal center with O2•−. We used three ligands differing in their …

Pursuing the Elixir of Life: In vivo antioxidative effects of manganosalen complexes

L Rouco, AM González-Noya, R Pedrido, M Maneiro - Antioxidants, 2020 - mdpi.com
Manganosalen complexes are coordination compounds that possess a chelating salen-type
ligand, a class of bis-Schiff bases obtained by condensation of salicylaldehyde and a …

Synthesis, crystal structure and magnetic properties of a pentanuclear Mn (III) cluster with 1, 2, 4-triazole based Schiff base ligand

R Bikas, P Mirzakhani, N Noshiranzadeh… - Inorganica Chimica …, 2020 - Elsevier
The reaction of equimolar amounts of 2-hydroxy-5-iodobenzaldehyde and 5-(methylthio)-1H-
1, 2, 4-triazol-3-amine in methanol yielded a new 1, 2, 4-triazole based Schiff base ligand, H …

The effect of the orientation of the Jahn–Teller distortion on the magnetic interactions of trinuclear mixed-valence Mn (II)/Mn (III) complexes

R Bikas, E Shahmoradi, S Reinoso, M Emami… - Dalton …, 2019 - pubs.rsc.org
Two new trinuclear manganese complexes,[Mn3 (L1)(μ-OCH3) 2 (N3) 2]· CH3OH (1) and
[Mn3 (L2)(μ-OCH3) 2 (N3) 2]· CH3OH (2), have been obtained from the reaction of Mn (OAc) …

[HTML][HTML] Neuroprotective effects of fluorophore-labelled manganese complexes: Determination of ROS production, mitochondrial membrane potential and confocal …

L Rouco, R Alvariño, A Alfonso, MJ Romero… - Journal of Inorganic …, 2022 - Elsevier
In this work, four manganese (II) complexes derived from the ligands H 2 L 1-H 2 L 4, that
incorporate dansyl or tosyl fluorescent dyes, have been investigated in term of their …