Using nature's blueprint to expand catalysis with Earth-abundant metals

RM Bullock, JG Chen, L Gagliardi, PJ Chirik, OK Farha… - Science, 2020 - science.org
BACKGROUND Catalysis has had a transformative impact on society, playing a crucial role
in the production of modern materials, medicines, fuels, and chemicals. Precious metals …

Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems

AA Gewirth, JA Varnell, AM DiAscro - Chemical reviews, 2018 - ACS Publications
A comprehensive review of recent advances in the field of oxygen reduction electrocatalysis
utilizing nonprecious metal (NPM) catalysts is presented. Progress in the synthesis and …

Electrocatalysis of single-atom sites: impacts of atomic coordination

B Lu, Q Liu, S Chen - Acs Catalysis, 2020 - ACS Publications
Single metal atoms embedded within select supporting matrices have shown great potential
in the development of high-efficiency, low-cost electrocatalysts because of maximal atom …

Electroactive covalent organic frameworks: design, synthesis, and applications

Y Yusran, Q Fang, V Valtchev - Advanced Materials, 2020 - Wiley Online Library
Covalent organic frameworks (COFs) are an emerging class of crystalline porous polymers
with tailorable compositions, porosities, functionalities, and intrinsic chemical stability. The …

Copper–oxygen complexes revisited: structures, spectroscopy, and reactivity

CE Elwell, NL Gagnon, BD Neisen, D Dhar… - Chemical …, 2017 - ACS Publications
A longstanding research goal has been to understand the nature and role of copper–oxygen
intermediates within copper-containing enzymes and abiological catalysts. Synthetic …

Multicopper laccase mimicking nanozymes with nucleotides as ligands

H Liang, F Lin, Z Zhang, B Liu, S Jiang… - … applied materials & …, 2017 - ACS Publications
Using nanomaterials to achieve functional enzyme mimics (nanozymes) is attractive for both
applied and fundamental research. Laccases are multicopper oxidases highly important for …

Recent development on metal phthalocyanines based materials for energy conversion and storage applications

A Kumar, VK Vashistha, DK Das - Coordination Chemistry Reviews, 2021 - Elsevier
Owing to the rapid decline of fossil fuels and related deleterious consequences throughout
the globe, energy use is undergoing a significant and dramatic transition into electricity as …

Molecular electrocatalysts for the oxygen reduction reaction

S Dey, B Mondal, S Chatterjee, A Rana… - Nature Reviews …, 2017 - nature.com
The past decade has seen considerable growth in the development of materials for fuel cell
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …

Molecular control of carbon‐based oxygen reduction electrocatalysts through metal macrocyclic complexes functionalization

Y Hong, L Li, B Huang, X Tang, W Zhai… - Advanced Energy …, 2021 - Wiley Online Library
Owing to their zero pollution and high efficiency, fuel cells and metal–air batteries show
great potential for broad application to sustainable energy technologies. However, the use of …

Facile synthesis of surfactant-free Au cluster/graphene hybrids for high-performance oxygen reduction reaction

H Yin, H Tang, D Wang, Y Gao, Z Tang - Acs Nano, 2012 - ACS Publications
Non-Pt noble metal clusters like Au clusters are believed to be promising high performance
catalysts for the oxygen reduction reaction (ORR) at the cathode of fuel cells, but they still …