Three-Component Photochemical 1, 2, 5-Trifunctionalizations of Alkenes toward Densely Functionalized Lynchpins

F Paulus, C Stein, C Heusel, TJ Stoffels… - Journal of the …, 2023 - ACS Publications
Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

Photoredox-Catalyzed Strain-Release-Driven Synthesis of Functionalized Spirocyclobutyl Oxindoles

T Singha, NA Bapat, SK Mishra, DP Hari - Organic Letters, 2024 - ACS Publications
Spirocyclobutyl oxindoles have garnered substantial attention in drug discovery and
pharmaceuticals owing to their wide range of biological activities. Strain-release in small …

Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Q Zeng, Y Gong, X He, X Zhang, Z Lian - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
β-Amino sulfones find extensive applications in pharmaceuticals, natural products,
agrochemicals, and organic synthesis. Meanwhile, aziridine units are recognized as …

Photoinduced EnT-mediated sulfonamidylimination of alkenes and (hetero) arenes with iminophenylacetic acid oxime esters

Z Sun, J Zhang, X Du, L Liu, S Gao, C Qi… - Chemical …, 2024 - pubs.rsc.org
A photoinduced EnT-mediated generation of sulfonamidyl radicals has been accomplished
using rationally designed iminophenylacetic acid oxime ester reagents under metal-free …

Photocatalytic Synthesis and Functionalization of Sulfones, Sulfonamides and Sulfoximines

JJ Garrido‐González, K Medrano‐Uribe… - … A European Journal, 2024 - Wiley Online Library
Sulfur (VI)‐based functional groups are popular scaffolds in a wide variety of research fields
including synthetic and medicinal chemistry, as well as chemical biology. The growing …

Visible-Light-Induced Decarboxylative Aminosulfonylation of (Hetero) aryl Carboxylic Oxime Esters

Z Zhuang, Y Sun, Y Zhong, Q He, X Zhang… - Organic Letters, 2024 - ACS Publications
Sulfonamides are important structures in pharmaceuticals, agrochemicals, and
organocatalysts, yet the rapid and benign synthesis of these compounds is still a great …

Visible-Light-Induced Energy-Transfer-Mediated Hydrofunctionalization and Difunctionalization of Unsaturated Compounds via Sigma-Bond Homolysis of Energy …

Q Sun, SP Wang, Y Xu, A Yin, L Yang, J Zhu… - ACS …, 2025 - ACS Publications
Over the past decade, visible-light-mediated energy-transfer (EnT) catalysis, particularly
triplet–triplet energy-transfer (TTEnT) catalysis, has emerged as a mild and environmentally …

Photosensitized 1, 2-Difunctionalization of Alkenes to Access β-Amino Sulfonamides

ZL Xiao, ZZ Xie, CP Yuan, KY Deng, K Chen… - Organic …, 2024 - ACS Publications
A metal-free photosensitized 1, 2-imino-sulfamoylation of olefins by employing a tailor-made
sulfamoyl carbamate as the difunctionalization reagent has been established. This protocol …

Regio-and Stereoselective β-Sulfonylamination of Alkynes via Photosensitized Bifunctional N–S Bond Homolysis

T Pu, SH Wu, L Cai, W Pu, Y Yuan, Z Zhuang… - Organic …, 2024 - ACS Publications
Nitrogen central radicals (NCRs) are versatile synthetic intermediates for creating functional
nitrogen-containing molecules. Herein, a photosensitized β-sulfonylamination of terminal …

Synthesis of bishomocubanone derivatives via visible‐light‐induced intramolecular [2+ 2] cycloaddition reaction

B Yan, Q Zhang, Y Ling, J Liu… - Advanced Synthesis & …, 2025 - Wiley Online Library
IIn this paper, a visible‐light‐induced intramolecular [2+ 2] cycloaddition has been revealed
to synthesize the bishomocubanone derivatives in moderate to excellent yield under mild …