Argentophilic interactions

H Schmidbaur, A Schier - Angewandte Chemie International …, 2015 - Wiley Online Library
The decade 1990–2000 saw a growing interest in aurophilic interactions in gold chemistry.
These interactions were found to influence significantly a variety of structural and other …

Hydrido-coinage-metal clusters: Rational design, synthetic protocols and structural characteristics

C Sun, BK Teo, C Deng, J Lin, GG Luo, CH Tung… - Coordination Chemistry …, 2021 - Elsevier
Ligated hydrido-coinage-metal clusters M x H y L z (M= Cu/Ag/Au, L= ligand; where x, y, and
z are positive integers) often exhibit interesting catalytic properties, and serve as ideal …

Coinage metal hydrides: synthesis, characterization, and reactivity

AJ Jordan, G Lalic, JP Sadighi - Chemical Reviews, 2016 - ACS Publications
Hydride complexes of copper, silver, and gold encompass a broad array of structures, and
their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis …

Polyhydrido copper clusters: synthetic advances, structural diversity, and nanocluster-to-nanoparticle conversion

RS Dhayal, WE van Zyl, CW Liu - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Metal hydride clusters have historically been studied to unravel their
aesthetically pleasing molecular structures and interesting properties, especially toward …

[Ag21{S2P(OiPr)2}12]+: An Eight‐Electron Superatom

RS Dhayal, JH Liao, YC Liu, MH Chiang… - Angewandte …, 2015 - Wiley Online Library
A novel discrete [Ag21 {S2P (OiPr) 2} 12](PF6) nanocluster has been synthesized and
characterized by single‐crystal X‐ray diffraction and also NMR spectroscopy (1H, 31P), ESI …

All-Carboxylate-Protected Superatomic Silver Nanocluster with an Unprecedented Rhombohedral Ag8 Core

KG Liu, XM Gao, T Liu, ML Hu… - Journal of the American …, 2020 - ACS Publications
We report the synthesis and structure of the first all-carboxylate-protected superatomic silver
nanocluster. It was prepared by heating a dimethylformamide solution of perfluoroglutaric …

Recent progress in dichalcophosphate coinage metal clusters and superatoms

AV Artem'ev, CW Liu - Chemical Communications, 2023 - pubs.rsc.org
Atomically precise clusters of group 11 metals (Cu, Ag, and Au) attract considerable
attention owing to their remarkable structure and fascinating properties. One of the unique …

Chinese puzzle molecule: A 15 hydride, 28 copper atom nanoball

AJ Edwards, RS Dhayal, PK Liao, JH Liao… - Angewandte …, 2014 - Wiley Online Library
The syntheses of the first rhombicuboctahedral copper polyhydride complexes [Cu28 (H) 15
(S2CNR) 12] PF6 (NR= NnPr2 or aza‐15‐crown‐5) are reported. These complexes were …

Argentophile Wechselwirkungen

H Schmidbaur, A Schier - Angewandte Chemie, 2015 - Wiley Online Library
Zwischen 1990 und 2000 wuchs in der Goldchemie das Interesse an aurophilen
Wechselwirkungen, nachdem man festgestellt hatte, dass diese eine Vielzahl struktureller …

Diselenophosphate‐Induced Conversion of an Achiral [Cu20H11{S2P(OiPr)2}9] into a Chiral [Cu20H11{Se2P(OiPr)2}9] Polyhydrido Nanocluster

RS Dhayal, JH Liao, X Wang, YC Liu… - Angewandte Chemie …, 2015 - Wiley Online Library
A polyhydrido copper nanocluster,[Cu20H11 {Se2P (OiPr) 2} 9](2H), which exhibits an
intrinsically chiral inorganic core of C3 symmetry, was synthesized from achiral [Cu20H11 …