Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Asymmetric phosphine catalysis showcasing remarkable progress over the past two
decades has emerged as a key synthetic platform for the creation of molecular frameworks …

Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

Chiral phosphines are versatile Lewis basic catalysts that are capable of promoting a wide
range of asymmetric reactions. In particular, recently designed chiral phosphines based on …

Phosphine‐catalyzed enantioselective annulation reactions involving ketimines are a
daunting synthetic challenge owing to the intrinsic low reactivity of ketimine substrates. A …

The goal of this review is to collect the recent developments in asymmetric organocatalytic
(aza)-Morita− Baylis− Hillman reactions reported since the beginning of 2013. It also …

We report the highly enantioselective synthesis of P-chiral tertiary phosphine oxides
featuring an ethynyl group via Cu (I)-catalyzed azide–alkyne cycloaddition. Newly …

Abstract An enantio‐, diastereo‐, regio‐, and chemoselective phosphine‐catalyzed β, γ‐
umpolung domino reaction of allenic esters with dienones has been developed for the first …

Catalytic enantioselective synthesis methodologies have been actively explored and
developed owing to the significance of chiral molecules and their utilities. In particular …