Regulating nonmetallic species beyond the first coordination shell of single-atom catalysts for high-performance electrocatalysis

W Ni, H Chen, J Zeng, Y Zhang, HA Younus… - Energy & …, 2023 - pubs.rsc.org
The local microenvironment of single-atom electrocatalysts (SACs) governs their activity and
selectivity. While previous studies have focused on the first coordination shell (FCS) of metal …

Dynamic Evolution of Active Sites in Electrocatalytic CO2 Reduction Reaction: Fundamental Understanding and Recent Progress

W Lai, Z Ma, J Zhang, Y Yuan, Y Qiao… - Advanced Functional …, 2022 - Wiley Online Library
Advancing the development of electrocatalytic CO2 reduction reaction (CO2RR) to address
the environmental issues caused by excessive consumption of fossil fuels requires rational …

Unraveling the Electronic Structure and Dynamics of the Atomically Dispersed Iron Sites in Electrochemical CO2 Reduction

Y Zeng, J Zhao, S Wang, X Ren, Y Tan… - Journal of the …, 2023 - ACS Publications
Single-atom catalysts with a well-defined metal center open unique opportunities for
exploring the catalytically active site and reaction mechanism of chemical reactions …

A Two-Dimensional van der Waals Heterostructure with Isolated Electron-Deficient Cobalt Sites toward High-Efficiency CO2 Electroreduction

H Gu, G Shi, L Zhong, L Liu, H Zhang… - Journal of the …, 2022 - ACS Publications
Electrochemical CO2 conversion is a promising way for sustainable chemical fuel
production, yet the conversion efficiency is strongly limited by the sluggish kinetics and …

Single atom-based catalysts for electrochemical CO2 reduction

Q Sun, C Jia, Y Zhao, C Zhao - Chinese Journal of Catalysis, 2022 - Elsevier
Electrochemical CO 2 reduction reaction (CO 2 RR), powered by renewable energy,
emerges as a promising approach against environmental issues and energy crisis by …

In situ electrochemical characterization of CuxO-based gas-diffusion electrodes (GDEs) for CO2 electrocatalytic reduction in presence and absence of liquid …

D Giusi, M Miceli, C Genovese, G Centi… - Applied Catalysis B …, 2022 - Elsevier
Copper oxide-based gas-diffusion electrodes (Cu x O/GDEs) for CO 2 electrocatalytic
reduction are investigated in presence and absence of liquid electrolyte (liquid-and gas …

Self-Assembled Liposomes Enhance Electron Transfer for Efficient Photocatalytic CO2 Reduction

S Rodríguez-Jiménez, H Song, E Lam… - Journal of the …, 2022 - ACS Publications
Light-driven conversion of CO2 to chemicals provides a sustainable alternative to fossil
fuels, but homogeneous systems are typically limited by cross reactivity between different …

Product distribution control guided by a microkinetic analysis for CO reduction at high-flux electrocatalysis using gas-diffusion Cu electrodes

X Lu, T Shinagawa, K Takanabe - ACS Catalysis, 2023 - ACS Publications
In addition to the identity of the electrocatalyst materials, the catalytic performance is strongly
influenced by the local steady-state environment perturbed by reaction conditions (pressure …

Revealing a Double‐Volcano‐Like Structure‐Activity Relationship for Substitution‐Functionalized Metal‐Phthalocyanine Catalysts toward Electrochemical CO2 …

W Zhu, S Liu, K Zhao, G Ye, K Huang, Z He - Small, 2024 - Wiley Online Library
Abstract Electron‐donating/‐withdrawing groups (EDGs/EWGs) substitution is widely used to
regulate the catalytic performance of transition‐metal phthalocyanine (MPc) toward …

Phthalocyanine and porphyrin catalysts for electrocatalytic reduction of carbon dioxide: Progress in regulation strategies and applications

J Zhao, H Lyu, Z Wang, C Ma, S Jia, W Kong… - Separation and …, 2023 - Elsevier
Electrocatalytic reduction of CO 2 (eCO 2 RR) is an effective way to convert CO 2 into value-
added products. As an important branch of eCO 2 RR, molecular catalysts have been …