The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Transition state search is at the center of multiple types of computational chemical
predictions related to mechanistic investigations, reactivity and regioselectivity predictions …

Transition-metal-catalyzed [4+ 1] reaction of dienes and carbon monoxide (CO) is the most
straightforward and easily envisioned cyclization for the synthesis of five-membered …

Ammonium ylides have a long history in organic synthesis, but their application in
asymmetric catalysis is still underdeveloped in regard to both substrate scope and reaction …

The synthesis, characterization, and reactivity of an aluminum alkoxide complex supported
by a ferrocene-based ligand,(thiolfan*) Al (O t Bu)(1 red, thiolfan*= 1, 1′-di (2, 4-di-tert-butyl …

A diversity-oriented synthesis of bioactive benzanilides via C (sp2)–H hydroxylation has
been studied. Different regioselectivity was observed with Ru (II) and Pd (II) catalysts. The …

Ene-allenes serve as versatile building blocks in organic synthesis, and the development of
their efficient preparation is valuable. Herein the synthesis of boryl-substituted ene-allenes …

The impact of the metal size and Lewis acidity on the polymerization activity of group 13
metal complexes was studied, and it was shown that, within the same ligand family, indium …

Two epoxidation catalysts, one of which consists of two VANOL ligands and an aluminum
and the other that consists of two VANOL ligands and a boron, were compared. Both …

Density functional theory calculations were performed to study the effects of N-heterocyclic
carbene (NHC) ligands on the Rh-catalyzed hydroboration of styrene and to identify factors …