Design, synthesis and excited-state properties of mononuclear Ru (II) complexes of tridentate heterocyclic ligands

AK Pal, GS Hanan - Chemical Society Reviews, 2014 - pubs.rsc.org
Artificial photosynthetic systems that contain light-harvesting coordination complexes may
one day replace conventional non-renewable sources of energy with renewable solar …

Enhancing the photophysical properties of Ru (II) complexes by specific design of tridentate ligands

MT Rupp, N Shevchenko, GS Hanan… - Coordination Chemistry …, 2021 - Elsevier
Artificial photosynthetic systems can collect and transform solar energy into chemical
energy. Inspired by natural photosynthesis, molecular artificial systems are commonly …

Blue‐Emissive Cobalt (III) Complexes and Their Use in the Photocatalytic Trifluoromethylation of Polycyclic Aromatic Hydrocarbons

AK Pal, C Li, GS Hanan… - Angewandte …, 2018 - Wiley Online Library
Room‐temperature luminescent CoIII complexes (1 and 2) are presented that exhibit intense
ligand‐to‐metal and ligand‐to‐ligand charge transfer absorption in the low‐energy UV …

Photocatalytic hydrogen evolution driven by a heteroleptic ruthenium (II) bis (terpyridine) complex

M Rupp, T Auvray, E Rousset, GM Mercier… - Inorganic …, 2019 - ACS Publications
Since the initial report by Lehn et al. in 1979, ruthenium tris (bipyridine)([Ru (bpy) 3] 2+) and
its numerous derivatives were applied as photosensitizers (PSs) in a large panel of …

Ruthenium Azobis (benzothiazole): Electronic Structure and Impact of Substituents on the Electrocatalytic Single-Site Water Oxidation Process

A Singh, B Singh, S Dey, A Indra, GK Lahiri - Inorganic Chemistry, 2023 - ACS Publications
The present article deals with the structurally and spectroelectrochemically characterized
newer class of ruthenium-azoheteroarenes [RuII (Ph-trpy)(Cl)(L)] ClO4,[1] ClO4–[3] ClO4 (Ph …

Panchromatic Absorption and Oxidation of an Iron (II) Spin Crossover Complex

J Moll, C Förster, A König, LM Carrella… - Inorganic …, 2022 - ACS Publications
In order to expand and exploit the useful properties of d6-iron (II) and d5-iron (III) complexes
in potential magnetic, photophysical, or magnetooptical applications, crucial ligand …

Coupled Potential Energy Surfaces Strongly Impact the Lowest-Energy Spin-Flip Transition in Six-Coordinate Nickel (II) Complexes

NR East, C Dab, C Förster, K Heinze… - Inorganic …, 2023 - ACS Publications
Luminescent complexes of earth-abundant first-row transition metals are of renewed, broad
interest due to their spectroscopic and photochemical properties as well as emerging …

pH-switchable “Off–On–Off” near-infrared luminescence based on a dinuclear ruthenium (II) complex

TT Meng, H Wang, ZB Zheng, KZ Wang - Inorganic Chemistry, 2017 - ACS Publications
The pH-switchable room-temperature near-infrared (NIR) phosphorescence emission based
on ruthenium (II) polypyridyl complexes has been very rarely reported, even though it is very …

Near infra-red emitting Ru (II) complexes of tridentate ligands: electrochemical and photophysical consequences of a strong donor ligand with large bite angles

AK Pal, S Serroni, N Zaccheroni, S Campagna… - Chemical …, 2014 - pubs.rsc.org
A novel N^ N^ N tridentate ligand dgpy (dgpy= 2, 6-diguanidylpyridine) was synthesized by
a Pd-catalyzed C–N bond-forming reaction. A novel family of [RuII (tpy')(dgpy)](PF6) 2 (1 and …

Red-light-driven photocatalytic hydrogen evolution using a ruthenium quaterpyridine complex

E Rousset, D Chartrand, I Ciofini, V Marvaud… - Chemical …, 2015 - pubs.rsc.org
A high-temperature, microwave synthesis of [Ru (qpy) 3] 2+(qpy= 4, 4′: 2′, 2′′: 4′′,
4′′′-quaterpyridine) affords the photosensitiser in quantitative yield. The complex …