Photocatalytic late-stage C–H functionalization

P Bellotti, HM Huang, T Faber, F Glorius - Chemical Reviews, 2023 - ACS Publications
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …

Enantioselective radical reactions using chiral catalysts

S Mondal, F Dumur, D Gigmes, MP Sibi… - Chemical …, 2022 - ACS Publications
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Photoelectrochemical asymmetric catalysis enables site-and enantioselective cyanation of benzylic C–H bonds

CY Cai, XL Lai, Y Wang, HH Hu, J Song, Y Yang… - Nature Catalysis, 2022 - nature.com
The enantioselective functionalization of ubiquitous C (sp 3)–H bonds is ideally suited for
the construction of three-dimensional chiral structures. However, organic molecules often …

Copper-catalyzed radical relay in C (sp 3)–H functionalization

Z Zhang, P Chen, G Liu - Chemical Society Reviews, 2022 - pubs.rsc.org
Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …

Radical C(sp3)–H functionalization and cross-coupling reactions

DL Golden, SE Suh, SS Stahl - Nature Reviews Chemistry, 2022 - nature.com
C–H functionalization reactions are playing an increasing role in the preparation and
modification of complex organic molecules, including pharmaceuticals, agrochemicals and …

[PDF][PDF] Photoinduced intermolecular hydrogen atom transfer reactions in organic synthesis

H Cao, X Tang, H Tang, Y Yuan, J Wu - Chem Catalysis, 2021 - cell.com
Hydrogen-atom transfer (HAT) provides straightforward methods to generate open-shell
radical intermediates from RH (R= C, Si, etc.) bonds and offers unique opportunities for …

Nickel-catalyzed enantioselective electrochemical reductive cross-coupling of aryl aziridines with alkenyl bromides

X Hu, I Cheng-Sánchez… - Journal of the …, 2023 - ACS Publications
An electrochemically driven nickel-catalyzed enantioselective reductive cross-coupling of
aryl aziridines with alkenyl bromides has been developed, affording enantioenriched β-aryl …

Metallaphotoredox catalysis for sp 3 C–H functionalizations through hydrogen atom transfer (HAT)

J Zhang, M Rueping - Chemical Society Reviews, 2023 - pubs.rsc.org
In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …

Nickel-catalyzed enantioselective reductive cross-coupling reactions

KE Poremba, SE Dibrell, SE Reisman - ACS catalysis, 2020 - ACS Publications
Nickel-catalyzed reductive cross-coupling reactions have emerged as powerful methods to
join two electrophiles. These reactions have proven particularly useful for the coupling of sec …

Paired electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling between α-chloroesters and aryl bromides

D Liu, ZR Liu, ZH Wang, C Ma, S Herbert… - Nature …, 2022 - nature.com
Electrochemical asymmetric catalysis has emerged as a sustainable and promising
approach to the production of chiral compounds and the utilization of both the anode and …