Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Electrocarboxylation of organic halides is one of the most investigated electrochemical
approaches for converting thermodynamically inert carbon dioxide (CO2) into value-added …

The benzyl group and its derivatives are the most frequently and widely utilized protective
groups in organic synthesis and are typically removed by traditional transition-metal …

Instantaneous Deprotection of Tosylamides and Esters with SmI2/Amine/Water | Organic
Letters ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS …

Here, we describe the formation and use of silyl cobalt (III) dihydride complexes as powerful
catalysts for the hydrosilylation of a variety of imines starting from a low-valent well-defined …

Chemoselective acidic hydrolysis of sulfonamides with trifluoromethanesulfonic acid has
been evaluated as a deprotection method and further extended to more complex synthetic …

Novel approaches for N-and O-desulfonylation under room temperature (rt) and transition-
metal-free conditions have been developed. The first methodology involves the …