[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Revealing hydrogen spillover pathways in reducible metal oxides

K Shun, K Mori, S Masuda, N Hashimoto, Y Hinuma… - Chemical …, 2022 - pubs.rsc.org
Hydrogen spillover, the migration of dissociated hydrogen atoms from noble metals to their
support materials, is a ubiquitous phenomenon and is widely utilized in heterogeneous …

Controlling CO2 Hydrogenation Selectivity by Metal‐Supported Electron Transfer

X Li, J Lin, L Li, Y Huang, X Pan… - Angewandte Chemie …, 2020 - Wiley Online Library
Tuning CO2 hydrogenation selectivity to obtain targeted value‐added chemicals and fuels
has attracted increasing attention. However, a fundamental understanding of the way to …

Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides

M Tan, Y Yang, Y Yang, J Chen, Z Zhang, G Fu… - Nature …, 2022 - nature.com
Spontaneous migration of atomic hydrogen species from metal particles to the surface of
their support, known as hydrogen spillover, has been claimed to play a major role in catalytic …

Synergistic effect of the metal-support interaction and interfacial oxygen vacancy for CO2 hydrogenation to methanol over Ni/In2O3 catalyst: A theoretical study

C Shen, Q Bao, W Xue, K Sun, Z Zhang, X Jia… - Journal of Energy …, 2022 - Elsevier
Indium oxide supported nickel catalyst has been experimentally confirmed to be highly
active for CO 2 hydrogenation towards methanol. In this work, the reaction mechanism for …

Supported Ni2P catalysts derived from nickel phyllosilicate with enhanced hydrodesulfurization performance

G Huang, Z Sun, Z Yu, YY Liu, Y Wang, W Wang… - Journal of …, 2023 - Elsevier
Highly dispersed Ni 2 P catalysts were prepared from nickel phyllosilicate precursor, which
was generated on the support by the deposition–precipitation (DP) method. Si-containing …

[HTML][HTML] Electronic distribution and dynamics as catalytic descriptors in heterogeneous catalysis: A mini review

Y Nzuzo, CO Oseghale, A Chike-Ekwughe… - Catalysis …, 2024 - Elsevier
We report the recent advances in heterogeneous catalysis with emphasis on electron
configurations as driving forces of the catalytic reactions. Several descriptors, including size …

Electrocatalytic Hydrogen Evolution at Full Atomic Utilization over ITO-Supported Sub-nano-Ptn Clusters: High, Size-Dependent Activity Controlled by Fluxional Pt …

S Kumari, T Masubuchi, HS White… - Journal of the …, 2023 - ACS Publications
A combination of density functional theory (DFT) and experiments with atomically size-
selected Pt n clusters deposited on indium-tin oxide (ITO) electrodes was used to examine …

Tuning the shape and crystal phase of TiO 2 nanoparticles for catalysis

W Zhao, Y Li, W Shen - Chemical Communications, 2021 - pubs.rsc.org
Synthesis of TiO2 nanoparticles with tunable shape and crystal phase has attracted
considerable attention for the design of highly efficient heterogeneous catalysts. Tailoring …

Unraveling active sites regulation and temperature-dependent thermodynamic mechanism in photothermocatalytic CO2 conversion with H2O

L Zhang, C Li, Y Liu, C Xu, Y Zhang - npj Computational Materials, 2024 - nature.com
In the photothermal synergistic catalytic conversion of CO2 and H2O, the catalyst harnesses
solar energy to accumulate heat, thereby elevating the reaction system's temperature. The …