A pyridine alkoxide chelate ligand that promotes both unusually high oxidation states and water-oxidation catalysis
Conspectus Water-oxidation catalysis is a critical bottleneck in the direct generation of solar
fuels by artificial photosynthesis. Catalytic oxidation of difficult substrates such as water …
fuels by artificial photosynthesis. Catalytic oxidation of difficult substrates such as water …
Enhanced degradation of micropollutants in a peracetic acid–Fe (III) system with picolinic acid
Activation of peracetic acid (PAA) with iron species is an emerging advanced oxidation
process (AOP). This study investigates the use of the chelating agent picolinic acid (PICA) to …
process (AOP). This study investigates the use of the chelating agent picolinic acid (PICA) to …
Picolinic acid-mediated catalysis of Mn (II) for peracetic acid oxidation processes: Formation of high-valent Mn species
Metal-based advanced oxidation processes (AOPs) with peracetic acid (PAA) have been
extensively studied to degrade micropollutants (MPs) in wastewater. Mn (II) is a commonly …
extensively studied to degrade micropollutants (MPs) in wastewater. Mn (II) is a commonly …
Deciphering the Novel Picolinate-Mn (II)/peroxymonosulfate System for Sustainable Fenton-like Oxidation: Dominance of the Picolinate-Mn (IV)-peroxymonosulfate …
L Niu, Z Luo, W Chen, X Zhong, H Zeng… - Environmental …, 2024 - ACS Publications
A highly efficient and sustainable water treatment system was developed herein by
combining Mn (II), peroxymonosulfate (PMS), and biodegradable picolinic acid (PICA). The …
combining Mn (II), peroxymonosulfate (PMS), and biodegradable picolinic acid (PICA). The …
Copper (II) complex with 6-methylpyridine-2-carboxyclic acid: experimental and computational study on the XRD, FT-IR and UV–Vis spectra, refractive index, band …
Crystal structure of the synthesized copper (II) complex with 6-methylpyridine-2-carboxylic
acid,[Cu (6-Mepic) 2· H 2 O]· H 2 O, was determined by XRD, FT-IR and UV–Vis …
acid,[Cu (6-Mepic) 2· H 2 O]· H 2 O, was determined by XRD, FT-IR and UV–Vis …
A cobalt (II) complex with 6-methylpicolinate: synthesis, characterization, second-and third-order nonlinear optical properties, and DFT calculations
A cobalt (II) complex of 6-methylpicolinic acid,[Co (6-Mepic) 2 (H 2 O) 2]· 2H 2 O, was
prepared and fully determined by single crystal X-ray crystal structure analysis as well as FT …
prepared and fully determined by single crystal X-ray crystal structure analysis as well as FT …
Tetranuclear Zn (II) complexes with ditopic picolinohydrazone ligands: Synthesis, crystal structure, spectroscopic studies, and Hirschfeld surface analysis
Z Zabihollahi, R Bikas, M Hossaini-Sadr… - Journal of Molecular …, 2022 - Elsevier
Two N-and O-donor hydrazone ligands,(E)-N'-(1-(4‑hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)
ethylidene) picolinohydrazide (H 2 L 1) and (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) …
ethylidene) picolinohydrazide (H 2 L 1) and (E)-N'-(4-oxo-4-phenylbutan-2-ylidene) …
A unique manganese (II) complex of 4-methoxy-pyridine-2-carboxylate: Synthesis, crystal structure, FT-IR and UV–Vis spectra and DFT calculations
Ö Tamer - Journal of Molecular Structure, 2017 - Elsevier
The first metal complex of 4-Methoxy-pyridine-2-carboxylic acid,[Mn (4-mpic) 2 (H 2 O) 2],
has been synthesized, and its crystal structure has been determined by X-Ray diffraction …
has been synthesized, and its crystal structure has been determined by X-Ray diffraction …
Stable iridium (IV) complexes of an oxidation-resistant pyridine-alkoxide ligand: highly divergent redox properties depending on the isomeric form adopted
The preparation of the facial and meridional isomers of [Ir (pyalk) 3](pyalk= 2-(2-pyridyl)
isopropanoate), as model complexes for a powerful water oxidation catalyst, is reported. The …
isopropanoate), as model complexes for a powerful water oxidation catalyst, is reported. The …
Synthesis, X-Ray crystal structure, photophysical characterization and nonlinear optical properties of the unique manganese complex with picolinate and 1, 10 …
The first manganese complex of picolinic acid (also known as 2-pyridinecarboxylic acid) and
1, 10 phenantroline has been synthesized, and its structure has been fully characterized by …
1, 10 phenantroline has been synthesized, and its structure has been fully characterized by …