Nitrogenases are responsible for biological nitrogen fixation, a crucial step in the biogeochemical nitrogen cycle. These enzymes utilize a two-component protein system and …
The multiscaling quantum mechanics/molecular mechanics (QM/MM) approach was introduced in 1976, while the extensive acceptance of this methodology started in the 1990s …
BM Hoffman, DR Dean, LC Seefeldt - Accounts of chemical …, 2009 - ACS Publications
“Nitrogen fixation”, the reduction of dinitrogen (N2) to two ammonia (NH3) molecules, by the Mo-dependent nitrogenase is essential for all life. Despite four decades of research, a …
Understanding the coordination of dinitrogen to iron is important for understanding biological nitrogen fixation as well as for designing synthetic systems that are capable of …
JJ Scepaniak, MD Fulton, RP Bontchev… - Journal of the …, 2008 - ACS Publications
We have isolated and structurally characterized a terminal iron nitrido complex supported by a bulky tris (carbene) borate ligand. The electronic structure of this complex reveals that the …
Nitrogenase is the sole enzyme responsible for the ATP‐dependent conversion of atmospheric dinitrogen into the bioavailable form of ammonia (NH3), making this protein …
Massively converting nitrogen gas to ammonia is a key process in modern agricultural and industrial fields. The conventional Haber–Bosch process for NH3 production has to be …
Der Zugang zu weiterführenden Informationen ist durch ein Literaturverzeichnis gegeben, das schwerpunktmäßig Übersichtsartikel, aber auch neuere Originalarbeiten enthält …
JA Villa, EE Ray, BM Barney - FEMS Microbiology Letters, 2014 - academic.oup.com
Microalgae are viewed as a potential future agricultural and biofuel feedstock and also provide an ideal biological means of carbon sequestration based on rapid growth rates and …