Mechanism of nitrogen fixation by nitrogenase: the next stage

BM Hoffman, D Lukoyanov, ZY Yang, DR Dean… - Chemical …, 2014 - ACS Publications
Nitrogen is an essential element contained in many biomolecules necessary to sustain life.
1, 2 This element is abundantly available in Earth's atmosphere in the form of dinitrogen …

The spectroscopy of nitrogenases

C Van Stappen, L Decamps, GE Cutsail III… - Chemical …, 2020 - ACS Publications
Nitrogenases are responsible for biological nitrogen fixation, a crucial step in the
biogeochemical nitrogen cycle. These enzymes utilize a two-component protein system and …

Review on the QM/MM methodologies and their application to metalloproteins

CE Tzeliou, MA Mermigki, D Tzeli - Molecules, 2022 - mdpi.com
The multiscaling quantum mechanics/molecular mechanics (QM/MM) approach was
introduced in 1976, while the extensive acceptance of this methodology started in the 1990s …

Climbing nitrogenase: toward a mechanism of enzymatic nitrogen fixation

BM Hoffman, DR Dean, LC Seefeldt - Accounts of chemical …, 2009 - ACS Publications
“Nitrogen fixation”, the reduction of dinitrogen (N2) to two ammonia (NH3) molecules, by the
Mo-dependent nitrogenase is essential for all life. Despite four decades of research, a …

Iron–dinitrogen coordination chemistry: dinitrogen activation and reactivity

JL Crossland, DR Tyler - Coordination Chemistry Reviews, 2010 - Elsevier
Understanding the coordination of dinitrogen to iron is important for understanding
biological nitrogen fixation as well as for designing synthetic systems that are capable of …

Structural and spectroscopic characterization of an electrophilic iron nitrido complex

JJ Scepaniak, MD Fulton, RP Bontchev… - Journal of the …, 2008 - ACS Publications
We have isolated and structurally characterized a terminal iron nitrido complex supported by
a bulky tris (carbene) borate ligand. The electronic structure of this complex reveals that the …

Biological nitrogen fixation in theory, practice, and reality: a perspective on the molybdenum nitrogenase system

SD Threatt, DC Rees - FEBS letters, 2023 - Wiley Online Library
Nitrogenase is the sole enzyme responsible for the ATP‐dependent conversion of
atmospheric dinitrogen into the bioavailable form of ammonia (NH3), making this protein …

Theoretical Screening of Single Atoms Supported on Two-Dimensional Nb2CN2 for Nitrogen Fixation

Y Kong, D Liu, H Ai, KH Lo, S Wang… - ACS Applied Nano …, 2020 - ACS Publications
Massively converting nitrogen gas to ammonia is a key process in modern agricultural and
industrial fields. The conventional Haber–Bosch process for NH3 production has to be …

[图书][B] Grundlagen der metallorganischen Komplexkatalyse

D Steinborn - 2007 - Springer
Der Zugang zu weiterführenden Informationen ist durch ein Literaturverzeichnis gegeben,
das schwerpunktmäßig Übersichtsartikel, aber auch neuere Originalarbeiten enthält …

Azotobacter vinelandii siderophore can provide nitrogen to support the culture of the green algae Neochloris oleoabundans and Scenedesmus sp. BA032

JA Villa, EE Ray, BM Barney - FEMS Microbiology Letters, 2014 - academic.oup.com
Microalgae are viewed as a potential future agricultural and biofuel feedstock and also
provide an ideal biological means of carbon sequestration based on rapid growth rates and …