Effects of confinement on material behaviour at the nanometre size scale

M Alcoutlabi, GB McKenna - Journal of Physics: Condensed …, 2005 - iopscience.iop.org
In this article, the effects of size and confinement at the nanometre size scale on both the
melting temperature, T m, and the glass transition temperature, T g, are reviewed. Although …

Polymer-silicate nanocomposites: model systems for confined polymers and polymer brushes

EP Giannelis, R Krishnamoorti, E Manias - Polymers in confined …, 1999 - Springer
The static and dynamic properties of polymer-layered silicate nanocomposites are
discussed, in the context of polymers in confined spaces and polymer brushes. A wide range …

Dynamics near free surfaces and the glass transition in thin polymer films: a view to the future

MD Ediger, JA Forrest - Macromolecules, 2014 - ACS Publications
The past 20 years have seen a substantial effort to understand dynamics and the glass
transition in thin polymer films. In this Perspective, we consider developments in this field …

[图书][B] Broadband dielectric spectroscopy

F Kremer, A Schönhals - 2002 - books.google.com
Page 1 Friedrich Kremer Andreas Schönhals Editors Broadband Dielectric Spectroscopy 400
glycerol 300 T -1 200 -2 -6 -3 -3 0 3 6 9 12 $ Springer log (v [Hz]) 0 1 ,,3 log Page 2 Page 3 …

[图书][B] Prediction of polymer properties

J Bicerano - 2002 - taylorfrancis.com
Highlighting a broad range multiscale modeling and methods for anticipating the
morphologies and the properties of interfaces and multiphase materials, this reference …

Spin coating of thin and ultrathin polymer films

DB Hall, P Underhill… - Polymer Engineering & …, 1998 - Wiley Online Library
The spin coating of thin (> 200 nm thick) and ultrathin (< 200 nm thick) polymer films is
examined in several solvents of varying volatility over a broad range of polymer solution …

Effect of free surfaces on the glass transition temperature of thin polymer films

JA Forrest, K Dalnoki-Veress, JR Stevens, JR Dutcher - Physical review letters, 1996 - APS
We report the first measurements of the glass transition temperature T g for thin freely
standing polystyrene (PS) films. We have used Brillouin light scattering to measure T g for …

[图书][B] X-ray scattering from soft-matter thin films: materials science and basic research

M Tolan, M Tolan - 1999 - Springer
The properties of soft-matter thin films (eg liquid films, polymer coatings, Langmuir-Blodgett
multilayers) nowadays play an important role in materials science. They are also very …

The glass transition in thin polymer films

JA Forrest, K Dalnoki-Veress - Advances in Colloid and Interface Science, 2001 - Elsevier
In this article, we present a detailed account of important recent developments in the rapidly
evolving area of glass transitions in thin polymer films. We review the case of polymer films …

Interface and chain confinement effects on the glass transition temperature of thin polymer films

JA Forrest, K Dalnoki-Veress, JR Dutcher - Physical Review E, 1997 - APS
We have used Brillouin light scattering and ellipsometry to measure the glass transition
temperature T g of thin polystyrene (PS) films as a function of the film thickness h for two …