Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Radicals are ubiquitously involved in numerous chemical and biological processes. They
exhibit unique chemical bonding and physical properties applicable to functional materials …

Covalent bonds share electron pairs between two atoms and make up the skeletons of most
organic compounds in single, double and triple bonds. In contrast, examples of one-electron …

Atomically precise copper nanoclusters (NCs) are of immense interest for a variety of
applications, but have remained elusive. Herein, we report the isolation of a copper …

Because of the typical instability of copper nanoclusters, atom-precise structural elucidation
of these nanoclusters has remained elusive. Herein, we report an air-and moisture-stable 23 …

The definition of the van der Waals crust as the spherical section between the atomic radius
and the van der Waals radius of an element is discussed and a survey of the application of …

Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

The copper‐catalyzed radical aminofluorination of styrenes with N‐
fluorobenzenesulfonimide (NFSI) is realized with high regioselectivity, thus affording …

The first structurally characterized copper cluster with a Cu13 centered cuboctahedral
arrangement, a model of the bulk copper fcc structure, was observed in [Cu13 (S2CNnBu2) …

Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …