Review on the accelerated and low-temperature polymerization of benzoxazine resins: addition polymerizable sustainable polymers

B Lochab, M Monisha, N Amarnath, P Sharma… - Polymers, 2021 - mdpi.com
Due to their outstanding and versatile properties, polybenzoxazines have quickly occupied a
great niche of applications. Developing the ability to polymerize benzoxazine resin at lower …

Polybenzoxazines in fabrication of separation membranes: A review

V Vatanpour, B Kiskan, B Zeytuncu… - Separation and Purification …, 2021 - Elsevier
The demand on developing new materials for fabricating polymeric membranes is growing
progressively in membrane science. Since, novel materials with high chemical, mechanical …

Benzoxazine-based thermoset with autonomous self-healing and shape recovery

M Arslan, B Kiskan, Y Yagci - Macromolecules, 2018 - ACS Publications
A novel approach is reported for self-healing of polybenzoxazine thermosets based on both
supramolecular attractions and metal–ligand interactions. The relating smart material was …

Propargylamine: an attractive amine source for designing high-performance benzoxazine resins with low polymerization temperatures

Y Liu, W Sheng, R Yin, K Zhang - Polymer Chemistry, 2021 - pubs.rsc.org
Aniline is a very common amine source for benzoxazine synthesis, but it generally results in
relatively high ring-opening polymerization temperatures. The exploration of alternative …

Facile strategy for room temperature knitting of sulfur in polybenzoxazine: A new class of solution processable copolymers

S Sahu, B Lochab - ACS Sustainable Chemistry & Engineering, 2022 - ACS Publications
Industrial applications of the upcoming class of high-performance biobased
polybenzoxazines are currently impeded by the requirement of high polymerization …

Sustainable framework of chitosan–benzoxazine with mutual benefits: Low curing temperature and improved thermal and mechanical properties

M Monisha, N Yadav, B Lochab - ACS Sustainable Chemistry & …, 2019 - ACS Publications
Polybenzoxazines (PBzs) are emerging as a highly promising and superior class of
thermoset polymers for a variety of applications. However, it remains a significant challenge …

Catalyzing benzoxazine polymerization with borohydrides to reduce the cure temperature and coloring

Z Deliballi, B Kiskan, Y Yagci - European Polymer Journal, 2022 - Elsevier
Sodium cyanoborohydride (NaCNBH 3) and sodium borohydride (NaBH 4) were used as
catalysts to lower the ring-opening polymerization (ROP) temperature of 1, 3-benzoxazines …

Advanced polymers from simple benzoxazines and phenols by ring-opening addition reactions

Z Deliballi, B Kiskan, Y Yagci - Macromolecules, 2020 - ACS Publications
Simple benzoxazines were mixed and reacted with various phenolics such as phenol, p-
nitrophenol, p-cresol, 1, 3-dihyroxybenzene (resorcinol), 1, 3, 5-trihydroxybenzene …

Light-settable polybenzoxazines for marine antifouling coatings

Q Chen, J Dai, P Cao, G Lu, X Liu - Progress in Organic Coatings, 2023 - Elsevier
Building benzoxazine coatings on large equipment is of great practical importance and
challenging. In this work, a main-chain type benzoxazine (MCBZ) resin that can be quickly …

Design, synthesis, flame retardancy and dielectric properties of novel aromatic hyperbranched benzoxazine

W Cai, H Wen, Z Wang, H Lu, H Liu, Y Wang… - Reactive and Functional …, 2022 - Elsevier
Two kinds of novel aromatic hyperbranched benzoxazines (HBs), HB-Tppa1 and HB-Tppa2,
were designed and prepared by using 1, 1, 1-tris (4-hydroxyphenyl) ethane (THPE), p …