Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Regulating cationic polymerization: From structural control to life cycle management

L Wu, B Rondon, S Dym, W Wang, K Chen… - Progress in Polymer …, 2023 - Elsevier
Cationic polymerization is a powerful strategy for the production of well-defined polymers
and advanced materials. In particular, the emergence of living cationic polymerization has …

Polymeric multimaterials by photochemical patterning of crystallinity

AK Rylski, HL Cater, KS Mason, MJ Allen, AJ Arrowood… - Science, 2022 - science.org
An organized combination of stiff and elastic domains within a single material can
synergistically tailor bulk mechanical properties. However, synthetic methods to achieve …

A Sustainable Wood‐Based Iron Photocatalyst for Multiple Uses with Sunlight: Water Treatment and Radical Photopolymerization

X Guo, X Zhao, X Luo, Y Pang, B Tian… - Angewandte Chemie …, 2023 - Wiley Online Library
A sustainable photocatalyst for use with multiple purpose comprising demethylated lignin
(Fe3O4@ D‐wood) was made by treatment of wood and iron oxide. Characterization …

Photo‐response with radical afterglow by regulation of spin populations and hole‐electron distributions

Y Yang, J Wang, J Yang, L Tong, D Li… - Angewandte Chemie …, 2023 - Wiley Online Library
No matter photoinduced organic radicals have been reported frequently, they are usually
non‐luminescent at ambient conditions. The internal mechanism on stability and electronic …

Photoredox Catalysis in Photocontrolled Cationic Polymerizations of Vinyl Ethers

RJ Sifri, Y Ma, BP Fors - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Advances in photocontrolled polymerizations have expanded the scope of
polymer architectures and structures that can be synthesized for various applications. The …

Monophosphoniums as effective photoredox organocatalysts for visible light-regulated cationic RAFT polymerization

Z Yang, J Chen, S Liao - ACS Macro Letters, 2022 - ACS Publications
Visible light-regulated metal-free polymerizations have attracted considerable attention for
macromolecular syntheses in recent years. However, few organic photocatalysts show high …

Fast living 3D printing via free radical promoted cationic RAFT polymerization

B Zhao, J Li, G Li, X Yang, S Lu, X Pan, J Zhu - Small, 2023 - Wiley Online Library
The application of reversible deactivation radical polymerization techniques in 3D printing is
emerging as a powerful method to build “living” polymer networks, which can be easily …

NIR-sensitized hybrid radical and cationic photopolymerization of several cyanines in combination with diaryliodonium bis (trifluoromethyl) sulfonyl imide

Q Wang, S Popov, V Strehmel, JS Gutmann… - Polymer …, 2023 - pubs.rsc.org
A series of cyanines carrying methine chains of different lengths and terminal moieties
exhibiting absorption between 750 and 930 nm reacted after excitation in the NIR region …

Photoinduced 3D printing through a combination of cationic and radical RAFT polymerization

B Zhao, J Li, Z Li, X Lin, X Pan, Z Zhang, J Zhu - Macromolecules, 2022 - ACS Publications
Photopolymerization-based three-dimensional (3D) printing techniques have been widely
utilized to fabricate polymeric materials with complex architectures. The application of …