Theoretical chemical kinetics in tropospheric chemistry: methodologies and applications

L Vereecken, DR Glowacki, MJ Pilling - Chemical reviews, 2015 - ACS Publications
Chemical kinetics is central in much of tropospheric chemistry and in modeling tropospheric
chemical processes. Chemical reaction rate coefficients and product yields have traditionally …

Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact

TA Stephenson, MI Lester - International Reviews in Physical …, 2020 - Taylor & Francis
Criegee intermediates are reactive species formed in the ozonolysis of alkenes. Their
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …

The physical chemistry of Criegee intermediates in the gas phase

DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …

Research frontiers in the chemistry of Criegee intermediates and tropospheric ozonolysis

CA Taatjes, DE Shallcross, CJ Percival - Physical Chemistry Chemical …, 2014 - pubs.rsc.org
The chemistry of carbonyl oxides, known as Criegee intermediates, is central to many
aspects of tropospheric chemistry. For decades it has been known that these reactive …

Ultraviolet Spectrum and Photochemistry of the Simplest Criegee Intermediate CH2OO

JM Beames, F Liu, L Lu, MI Lester - Journal of the American …, 2012 - ACS Publications
Ozonolysis of alkenes in the troposphere produces Criegee intermediates, which have
eluded detection in the gas phase until very recently. This laboratory has synthesized the …

Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH2OO

L Sheps - The Journal of Physical Chemistry Letters, 2013 - ACS Publications
We present the time-resolved UV absorption spectrum of the B̃ (1A′)← X̃ (1A′) electronic
transition of formaldehyde oxide, CH2OO, produced by the reaction of CH2I radicals with …

[HTML][HTML] Perspective: Spectroscopy and kinetics of small gaseous Criegee intermediates

YP Lee - The Journal of chemical physics, 2015 - pubs.aip.org
The Criegee intermediates, carbonyl oxides proposed by Criegee in 1949 as key
intermediates in the ozonolysis of alkenes, play important roles in many aspects of …

A kinetic study of the CH 2 OO Criegee intermediate self-reaction, reaction with SO 2 and unimolecular reaction using cavity ring-down spectroscopy

R Chhantyal-Pun, A Davey, DE Shallcross… - Physical Chemistry …, 2015 - pubs.rsc.org
Criegee intermediates are important species formed during the ozonolysis of alkenes.
Reaction of stabilized Criegee intermediates with various species like SO2 and NO2 may …

Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO

R Chhantyal-Pun, O Welz, JD Savee… - The Journal of …, 2017 - ACS Publications
The Criegee intermediate acetone oxide,(CH3) 2COO, is formed by laser photolysis of 2, 2-
diiodopropane in the presence of O2 and characterized by synchrotron photoionization …

UV spectroscopic characterization of an alkyl substituted Criegee intermediate CH3CHOO

JM Beames, F Liu, L Lu, MI Lester - The Journal of Chemical Physics, 2013 - pubs.aip.org
Ozonolysis of alkenes in the troposphere proceeds through a Criegee intermediate, or
carbonyl oxide, which has only recently been detected in the gas phase. The present study …