Gas‐phase basicities of polyfunctional molecules. Part 2: Saturated basic sites

G Bouchoux, JY Salpin - Mass Spectrometry Reviews, 2012 - Wiley Online Library
The present article is the second part of a general overview of the gas‐phase protonation
thermochemistry of polyfunctional molecules. The first part of the review (Mass Spectrom …

Orientation and absolute coverage of furan and 2, 5‐dihydrofuran on Ag (110) determined by near edge x‐ray absorption fine structure and x‐ray photoelectron …

JL Solomon, RJ Madix, J Stöhr - The Journal of chemical physics, 1991 - pubs.aip.org
The orientation, absolute coverage and core‐electron binding energies of furan (C4H4O)
and 2, 5‐dihydrofuran (C4H6O) on Ag (110) have been measured using near edge x‐ray …

Unstable enols in the gas phase. Preparation ionization, energies, and heats of formation of (E)-and (Z)-2-buten-2-ol, 2-methyl-1-propen-1-ol, and 3-methyl-2-buten-2 …

F Turecek, L Brabec, J Korvola - Journal of the American Chemical …, 1988 - ACS Publications
(£)-2-Buten-2-ol (1),(Z)-2-buten-2-ol (2), 2-methyl-1-propen-1-ol (3), and 3-methyl-2-buten-2-
ol (4) were prepared as transient species by flash-vacuum pyrolysis of the corresponding …

Does tetrahydrofuran ring open upon ionization and dissociation? A TPES and TPEPICO investigation

PM Mayer, MF Guest, L Cooper… - The Journal of …, 2009 - ACS Publications
The threshold photoelectron spectrum (TPES) of tetrahydrofuran (THF) is compared to that of
the unsaturated furan molecule. In general, there is a similarity in the orbital ionization profile …

The proton affinities of saturated and unsaturated heterocyclic molecules

S Kabli, ESE van Beelen, S Ingemann… - International Journal of …, 2006 - Elsevier
The proton affinities derived from G3-calculations of 23 five-membered ring heteroaromatic
molecules agree well with the experimentally determined values available in the literature …

Experimental study of the potential energy surface of the protonated cyclohexene oxide/cyclohexanone system. Isomerization, dissociation, and ion-molecule …

HI Kenttamaa, RR Pachuta, AP Rothwell… - Journal of the …, 1989 - ACS Publications
The structures and properties of gaseous protonated cyclohexene oxide and cyclohexanone
are studied by employing dissociation and ion-molecule reactions occurring in a triple …

Experimental and theoretical studies of the gas-phase protonation of vinyl ethers, vinyl sulfides, and vinyl selenides

K Osapay, J Delhalle, KM Nsunda, E Rolli… - Journal of the …, 1989 - ACS Publications
A series of nine chalcogen-substituted ethylenes (chalcogen= O, S, Se) have been
synthesized, and their gas-phase proton affinities (PA) were determined experimentally by …

Stereoelectronic effects in mass spectrometry

F Turec̆ek - International journal of mass spectrometry and ion …, 1991 - Elsevier
Simple bond dissociations and hydrogen rearrangements in gaseous cation radicals and
even-electron cations can be governed by stereoelectronic effects imposed by control …

Unimolecular depurination of protonated deoxyribonucleosides in the gas phase: a fast atom bombardment tandem mass spectrometric investigation

A Liguori, F Greco, G Sindona… - Organic mass …, 1990 - Wiley Online Library
The spontaneous or collision‐induced unimolecular dissociations of base‐protonated 2′‐
deoxyribonucleosides afford, in the gas phase and in the absence of solvent, high yields of …

Unimolecular reactions of ionized methyl allyl ether

RD Bowen, AD Wright, PJ Derrick - Organic mass spectrometry, 1992 - Wiley Online Library
The fragmentation of CH2 CHCH2OCH3+· cation‐radicals has been investigated by
means of 2H‐and 13C‐labelling experiments and by analysis of collision‐induced …