Molecularly Engineered Room-Temperature Phosphorescence for Biomedical Application: From the Visible toward Second Near-Infrared Window

B Chang, J Chen, J Bao, T Sun, Z Cheng - Chemical Reviews, 2023 - ACS Publications
Phosphorescence, characterized by luminescent lifetimes significantly longer than that of
biological autofluorescence under ambient environment, is of great value for biomedical …

The hyperporphyrin concept: A contemporary perspective

CC Wamser, A Ghosh - JACS Au, 2022 - ACS Publications
The Gouterman four-orbital model conceptualizes porphyrin UV–visible spectra as
dominated by four frontier molecular orbitals─ two nearly degenerate HOMOs and two …

Designer heme proteins: Achieving novel function with abiological heme analogues

CM Lemon, MA Marletta - Accounts of chemical research, 2021 - ACS Publications
Conspectus Heme proteins have proven to be a convenient platform for the development of
designer proteins with novel functionalities. This is achieved by substituting the native iron …

Luminescence and palladium: The odd couple

D Dalmau, EP Urriolabeitia - Molecules, 2023 - mdpi.com
The synthesis, photophysical properties, and applications of highly fluorescent and
phosphorescent palladium complexes are reviewed, covering the period 2018–2022 …

Recent advances in the design and applications of platinum-based supramolecular architectures and macromolecules

BZ Momeni, AS Abd-El-Aziz - Coordination Chemistry Reviews, 2023 - Elsevier
Platinum complexes have attracted increasing attention because of their intriguing
photophysical and anticancer activities. They are considered excellent building blocks for …

Transition Metal Complexes as Antimalarial Agents: A Review

A Mandal, R Kushwaha, AA Mandal, S Bajpai… - …, 2023 - Wiley Online Library
In antimalarial drug development research, overcoming drug resistance has been a major
challenge for researchers. Nowadays, several drugs like chloroquine, mefloquine …

A DMRG/CASPT2 investigation of metallocorroles: quantifying ligand noninnocence in archetypal 3d and 4d element derivatives

QM Phung, Y Muchammad, T Yanai, A Ghosh - JACS Au, 2021 - ACS Publications
Hybrid density functional theory (B3LYP) and density matrix renormalization group (DMRG)
theory have been used to quantitatively compare the degree of ligand noninnocence …

Relativity and the World of Molecules

A Ghosh, K Ruud - American Scientist, 2023 - search.proquest.com
Ghosh and Ruud asserts that mention Albert Einstein's theory of relativity to people and it
commonly conjures up a sci-fi world of time travel and black holes. Relativity also plays a …

Regioselective formylation of rhenium-oxo and gold corroles: substituent effects on optical spectra and redox potentials

RF Einrem, ET Jonsson, SJ Teat, NS Settineri… - RSC …, 2021 - pubs.rsc.org
Vilsmeier–Haack formylation of ReO and Au meso-triarylcorroles over 16–18 hours affords
moderate to good yields (47–65%) of the ReO-3-formyl and Au-3, 17-diformyl derivatives in …

Relativity as a Synthesis Design Principle: A Comparative Study of [3+ 2] Cycloaddition of Technetium (VII) and Rhenium (VII) Trioxo Complexes with Olefins

H Braband, M Benz, B Spingler, J Conradie… - Inorganic …, 2021 - ACS Publications
The difference in [3+ 2] cycloaddition reactivity between fac-[MO3 (tacn)]+(M= Re, 99Tc;
tacn= 1, 4, 7-triazacyclononane) complexes has been reexamined with a selection of …