The ABC of generalized coordination numbers and their use as a descriptor in electrocatalysis

F Calle‐Vallejo - Advanced Science, 2023 - Wiley Online Library
The quest for enhanced electrocatalysts can be boosted by descriptor‐based analyses.
Because adsorption energies are the most common descriptors, electrocatalyst design is …

The role of morphology on the electrochemical CO2 reduction performance of transition metal-based catalysts

U Mustapha, CC Nnadiekwe, MA Alhaboudal… - Journal of Energy …, 2023 - Elsevier
The continued increase in population and the industrial revolution have led to an increase in
atmospheric carbon dioxide (CO 2) concentration. Consequently, developing and …

From Single Crystal to Single Atom Catalysts: Structural Factors Influencing the Performance of Metal Catalysts for CO2 Electroreduction

CD Koolen, W Luo, A Züttel - ACS Catalysis, 2022 - ACS Publications
With the electrochemical CO2 reduction reaction (CO2RR), CO2 can be used as a feedstock
to produce value-added chemicals and fuels while storing renewable energy. For its …

Stabilizing Undercoordinated Zn Active Sites through Confinement in CeO2 Nanotubes for Efficient Electrochemical CO2 Reduction

ST Guo, YW Du, H Luo, Z Zhu, T Ouyang… - Angewandte …, 2024 - Wiley Online Library
Zn‐based catalysts hold great potential to replace the noble metal‐based ones for CO2
reduction reaction (CO2RR). Undercoordinated Zn (Znδ+) sites may serve as the active sites …

Selective CO2‐to‐Syngas Conversion Enabled by Bimetallic Gold/Zinc Sites in Partially Reduced Gold/Zinc Oxide Arrays

R Zhao, Z Zhu, T Ouyang, ZQ Liu - Angewandte Chemie, 2024 - Wiley Online Library
Abstract Electrocatalytic CO2‐to‐syngas (gaseous mixture of CO and H2) is a promising way
to curb excessive CO2 emission and the greenhouse gas effect. Herein, we present a …

Efficient synthesis of syngas from CO2 electrochemical reduction over a dual functional FexC@ CNT/N-MXene catalyst

PP Guo, ZH He, HH Cao, K Wang, W Wang… - Applied Catalysis B …, 2024 - Elsevier
Syngas, composed of CO and H 2, is a crucial precursor for the synthesis of hydrocarbons
and aldehydes. Compared with traditional ways, the co-electrolysis of CO 2 and water …

Recent Progress on Electrode Design for Efficient Electrochemical Valorisation of CO2, O2, and N2

Z Lin, C Han, GEP O'Connell… - Angewandte Chemie …, 2023 - Wiley Online Library
CO2 reduction, two‐electron O2 reduction, and N2 reduction are sustainable technologies to
valorise common molecules. Their further development requires working electrode design to …

Evaluating the techno-economic potential of defossilized air-to-syngas pathways

HM Almajed, OJ Guerra, WA Smith… - Energy & …, 2023 - pubs.rsc.org
Defossilizing the chemical industry using air-to-chemical processes offers a promising
solution to driving down the emission trajectory to net-zero by 2050. Syngas is a key …

Enhanced Carbon Monoxide Electroreduction to >1 A cm−2 C2+ Products Using Copper Catalysts Dispersed on MgAl Layered Double Hydroxide Nanosheet …

S Kwon, J Zhang, R Ganganahalli… - Angewandte …, 2023 - Wiley Online Library
Cu catalysts are most apt for reducing CO (2) to multi‐carbon products in aqueous
electrolytes. To enhance the product yield, we can increase the overpotential and the …

Metal‐Organic Framework Derived Bi‐O‐Sn/C Nanostructure: Tailoring the Adsorption Site of Dominant Intermediate for Highly Efficient CO2 Electroreduction to …

N Wang, C Shao, R Zhang, Y Zhang, Z Min, B Chang… - Small, 2024 - Wiley Online Library
Electrochemical CO2 reduction into high‐value‐added formic acid/formate is an attractive
strategy to mitigate global warming and achieve energy sustainability. However, the …