Tetradentate Ligand's Chameleon-Like Behavior Offers Recognition of Specific Lanthanides

S Pramanik, B Li, DM Driscoll… - Journal of the …, 2024 - ACS Publications
The surging demand for high-purity individual lanthanides necessitates the development of
novel and exceptionally selective separation strategies. At the heart of these separation …

Emerging Rare Earth Element Separation Technologies

S Pramanik, S Kaur, I Popovs, AS Ivanov… - European Journal of …, 2024 - Wiley Online Library
Rare earth elements are essential for numerous clean energy applications, yet their mining,
separation, and processing pose significant environmental challenges. Traditional …

Potential for light-induced separation of critical rare-earth elements

AJ Ferguson, MK Gish - Trends in Chemistry, 2024 - cell.com
Current methods for separations of critical rare earth elements (REEs) require multi-step,
waste-generating procedures that lack the ability to selectively separate similarly sized ions …

Metadynamics investigation of lanthanide solvation free energy landscapes and insights into separations energetics

X Wang, AA Peroutka, DV Kravchuk, JC Shafer… - Chemical …, 2024 - pubs.rsc.org
Lanthanide ion solvation chemistry in nonaqueous phases is key to understanding and
developing effective separation processes for these critical materials. Due to the complexity …

Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database

S Li, S Jansone-Popova, D Jiang - Scientific Reports, 2024 - nature.com
Understanding lanthanide coordination chemistry can help develop new ligands for more
efficient separation of lanthanides for critical materials needs. The Cambridge Structural …

Changes in nitrate binding with lanthanides in BLPhen complexes

TDN Reddy, AS Ivanov, DM Driscoll… - Journal of Molecular …, 2023 - Elsevier
Preorganized ligands such as bis-lactam-1, 10-phenanthroline (BLPhen) offer unique
selectivity trends in solvent extraction of rare-earth ions, particularly from aqueous nitrate …

Development of 225Ac-doped biocompatible nanoparticles for targeted alpha therapy

M Toro-González, N Akingbesote, A Bible, D Pal… - Journal of …, 2024 - Springer
Targeted alpha therapy (TAT) relies on chemical affinity or active targeting using
radioimmunoconjugates as strategies to deliver α-emitting radionuclides to cancerous …

2D Ionic Liquid‐Like State of Charged Rare‐Earth Clusters on a Metal Surface

D Trainer, AT Lee, S Sarkar, V Singh… - Advanced …, 2024 - Wiley Online Library
Rare‐earth complexes are vital for separation chemistry and useful in many advanced
applications including emission and energy upconversion. Here, 2D rare‐earth clusters …

Solvent effects on extractant conformational energetics in liquid–liquid extraction: a simulation study of molecular solvents and ionic liquids

X Wang, S Nayak, RE Wilson, L Soderholm… - Physical Chemistry …, 2024 - pubs.rsc.org
Extractant design in liquid–liquid extraction (LLE) is a research frontier of metal ion
separations that typically focuses on the direct extractant–metal interactions. However, a …

Fabrication of precursor-regulated derived materials from metal-organic complex and metal-organic salt for promoting photocatalytic properties

B Li, WT Zhang, WL Duan, LL Zhang, J Luan - Inorganic Chemistry …, 2024 - Elsevier
Numerous investigations had focused on the photocatalytic activity of carbon-derived
materials employing metal–organic complex (MOC) and metal–organic salt (MOS) as …