2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules

BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …

Astrophysical detection of the helium hydride ion HeH+

R Güsten, H Wiesemeyer, D Neufeld, KM Menten… - Nature, 2019 - nature.com
During the dawn of chemistry,, when the temperature of the young Universe had fallen
below some 4,000 kelvin, the ions of the light elements produced in Big Bang …

Laboratory spectroscopy techniques to enable observations of interstellar ion chemistry

BA McGuire, O Asvany, S Brünken… - Nature Reviews …, 2020 - nature.com
Molecular ions have long been considered key intermediates in the evolution of molecular
complexity in the interstellar medium. However, owing to their reactivity and transient nature …

Cationic noble-gas hydrides: From ion sources to outer space

F Grandinetti - Frontiers in Chemistry, 2020 - frontiersin.org
Cationic species with noble gas (Ng)-hydrogen bonds play a major role in the gas-phase ion
chemistry of the group 18 elements. These species first emerged more than 90 years ago …

Accurate adiabatic correction in the hydrogen molecule

K Pachucki, J Komasa - The Journal of Chemical Physics, 2014 - pubs.aip.org
A new formalism for the accurate treatment of adiabatic effects in the hydrogen molecule is
presented, in which the electronic wave function is expanded in the James-Coolidge basis …

Infrared Signatures of the HHen+ and DHen+ (n = 3–6) Complexes

O Asvany, S Schlemmer, T Szidarovszky… - The Journal of …, 2019 - ACS Publications
Combination of a cryogenic ion-trap machine, operated at 4.7 K, with the free-electron-laser
FELIX allows the first experimental characterization of the unusually bright antisymmetric …

Spectroscopic signatures of HHe 2+ and HHe 3+

M Töpfer, A Jensen, K Nagamori, H Kohguchi… - Physical Chemistry …, 2020 - pubs.rsc.org
Using two different action spectroscopic techniques, a high-resolution quantum cascade
laser operating around 1300 cm− 1 and a cryogenic ion trap machine, the proton shuttle …

Computational characterization of astrophysical species: The case of noble gas hydride cations

MJ Montes de Oca-Estevez, R Prosmiti - Frontiers in Chemistry, 2021 - frontiersin.org
Theoretical–computational studies together with recent astronomical observations have
shown that under extreme conditions in the interstellar medium (ISM), complexes of noble …

Fingerprints of microscopic superfluidity in HHen+ clusters

AG Császár, T Szidarovszky, O Asvany… - Molecular …, 2019 - Taylor & Francis
The structures and the vibrational dynamics of the complexes HHe n+ are investigated
experimentally (via mass spectrometry (MS)) and at high levels of electronic-structure theory …

High-resolution trace gas detection by sub-Doppler noise-immune cavity-enhanced optical heterodyne molecular spectrometry: application to detection of acetylene in …

G Zhao, T Hausmaninger, FM Schmidt, W Ma… - Optics …, 2019 - opg.optica.org
A sensitive high-resolution sub-Doppler detecting spectrometer, based on noise-immune
cavity-enhanced optical heterodyne molecular spectrometry (NICE-OHMS), for trace gas …