Chemical Evolution of CO2 Ices under Processing by Ionizing Radiation: Characterization of Nonobserved Species and Chemical Equilibrium Phase with the …

S Pilling, GA Carvalho, WRM Rocha - The Astrophysical Journal, 2022 - iopscience.iop.org
Astrophysical ices are being exposed to ionizing radiation in space environments, which
trigger new reactions and desorption processes. In the lab, such processing by radiation has …

Direct detection of complex organic products in ultraviolet (Lyα) and electron-irradiated astrophysical and cometary ice analogs using two-step laser ablation and …

BL Henderson, MS Gudipati - The Astrophysical Journal, 2015 - iopscience.iop.org
As discovery of complex molecules and ions in our solar system and the interstellar medium
has proliferated, several groups have turned to laboratory experiments in an effort to …

Radiolysis of ammonia-containing ices by energetic, heavy, and highly charged ions inside dense astrophysical environments

S Pilling, ES Duarte, EF Da Silveira, E Balanzat… - Astronomy & …, 2010 - aanda.org
Deep inside dense molecular clouds and protostellar disks, interstellar ices are protected
from stellar energetic UV photons. However, X-rays and energetic cosmic rays can penetrate …

Chemical reactions induced in frozen formic acid by heavy ion cosmic rays

DPP Andrade, ALF de Barros, S Pilling… - Monthly Notices of …, 2013 - academic.oup.com
We studied the effects produced by the interaction of heavy ion cosmic rays with interstellar
and cometary organic molecules in the solid phase. Formic acid (HCOOH) ice at 15 K was …

Chemical evolution of electron-bombarded crystalline water ices at different temperatures using the procoda code

S Pilling, CH da Silveira… - Monthly Notices of the …, 2023 - academic.oup.com
Water ices are a common component of cold space environments, including molecular and
protostellar clouds, and the frozen surfaces of moons, planets, and comets. When exposed …

The effect of broadband soft X-rays in SO2-containing ices: implications on the photochemistry of ices toward young stellar objects

S Pilling, A Bergantini - The Astrophysical Journal, 2015 - iopscience.iop.org
We investigate the effects produced mainly by broadband soft X-rays up to 2 keV (plus fast
(∼ keV) photoelectrons and low-energy (∼ eV) induced secondary electrons) in the ice …

Radiolysis of amino acids by heavy and energetic cosmic ray analogues in simulated space environments: α-glycine zwitterion form

W Portugal, S Pilling, P Boduch… - Monthly Notices of …, 2014 - academic.oup.com
In this work, we studied the stability of the glycine molecule in the crystalline zwitterion form,
known as α-glycine (+ NH3CH2COO−), under the action of heavy cosmic ray analogues …

Radiation-induced transformations of matrix-isolated formic acid: evidence for the HCOOH→ HOCO+ H channel

SV Ryazantsev, VI Feldman - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
The effect of X-ray irradiation on the isolated formic acid molecules (HCOOH) in solid noble
gas matrices (Xe, Kr, Ar, and Ne) at very low temperatures (6 K) was first studied by FTIR …

Photolysis of CH3CN Ices by Soft X-rays: Implications for the Chemistry of Astrophysical Ices at the Surroundings of X-ray Sources

GA Carvalho, S Pilling - The Journal of Physical Chemistry A, 2020 - ACS Publications
In this work, broad-band soft X-ray (6–2000 eV) was employed to irradiate frozen acetonitrile
CH3CN, at the temperature 13 K, with different photon fluences up to 1.5× 1018 photons cm …

X-ray photodesorption from methanol ice

DPP Andrade, MLM Rocco… - Monthly Notices of the …, 2010 - academic.oup.com
The abundances of molecules and ions depend on the mechanisms of their formation and
destruction that can occur both in the gas phase and in the condensed phase on grain …