Smart N-heterocyclic carbene ligands in catalysis
E Peris - Chemical reviews, 2017 - ACS Publications
It is well-recognized that N-heterocyclic carbene (NHC) ligands have provided a new
dimension to the design of homogeneous catalysts. Part of the success of this type of ligands …
dimension to the design of homogeneous catalysts. Part of the success of this type of ligands …
Metal–ligand cooperation
JR Khusnutdinova, D Milstein - … Chemie International Edition, 2015 - Wiley Online Library
Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …
metal complexes both in synthetic and biological systems. MLC implies that both the metal …
Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
Metal–ligand bifunctional catalysis: the “accepted” mechanism, the issue of concertedness, and the function of the ligand in catalytic cycles involving hydrogen atoms
For years, following the ideas of Shvo and Noyori, the core assumption of metal–ligand
bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand …
bifunctional molecular catalysis has relied on the direct involvement of the chelating ligand …
Methanation of CO 2 and reverse water gas shift reactions on Ni/SiO 2 catalysts: the influence of particle size on selectivity and reaction pathway
HC Wu, YC Chang, JH Wu, JH Lin, IK Lin… - Catalysis Science & …, 2015 - pubs.rsc.org
Catalytic CO2 hydrogenation has been studied on both 0.5 wt% and 10 wt% Ni/SiO2
catalysts with particular focus on the production of CO and CH4. The large difference in Ni …
catalysts with particular focus on the production of CO and CH4. The large difference in Ni …
Aperture-Opening Encapsulation of a Transition Metal Catalyst in a Metal–Organic Framework for CO2 Hydrogenation
The aperture-opening process resulting from dissociative linker exchange in zirconium-
based metal–organic framework (MOF) UiO-66 was used to encapsulate the ruthenium …
based metal–organic framework (MOF) UiO-66 was used to encapsulate the ruthenium …
Selective CO2 Hydrogenation to Formic Acid with Multifunctional Ionic Liquids
The development of simple, cost-effective, and sustainable methods to transform CO2 into
feedstock chemicals is essential to reduce the dependence of the chemical industry on fossil …
feedstock chemicals is essential to reduce the dependence of the chemical industry on fossil …
CO2 Hydrogenation to Formate Catalyzed by Ru Coordinated with a N,P-Containing Polymer
B Chen, M Dong, S Liu, Z Xie, J Yang, S Li… - ACS …, 2020 - ACS Publications
Development of high-performance catalysts for carbon dioxide (CO2) hydrogenation is
crucial for CO2 utilization. Herein, a heterogeneous catalyst for CO2 hydrogenation to …
crucial for CO2 utilization. Herein, a heterogeneous catalyst for CO2 hydrogenation to …
Synthesis of cyclic carbonates from epoxides and carbon dioxide by using bifunctional one‐component phosphorus‐based organocatalysts
H Büttner, J Steinbauer, T Werner - ChemSusChem, 2015 - Wiley Online Library
Numerous bifunctional organocatalysts were synthesized and tested for the atom‐efficient
addition of carbon dioxide and epoxides to produce cyclic carbonates. These catalysts are …
addition of carbon dioxide and epoxides to produce cyclic carbonates. These catalysts are …
Metall‐Ligand‐Kooperation
JR Khusnutdinova, D Milstein - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Die Metall‐Ligand‐Kooperation (MLC) hat sich zu einem wichtigen Konzept in der
Übergangsmetallkatalyse in synthetischen und biologischen Systemen entwickelt. MLC …
Übergangsmetallkatalyse in synthetischen und biologischen Systemen entwickelt. MLC …