This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

The development of organometallic catalysis has greatly expanded the synthetic chemist
toolbox compared to only exploiting “classical” organic chemistry. Although more widely …

Platinum-containing drugs (eg, cisplatin) are among the most frequently used
chemotherapeutic agents. Their tremendous success has spurred research and …

Besides the noble physical appearance of gold and silver, their novel chemical properties
attracted the modern technology for various industrial, chemical and biological uses …

Metal complex catalysis within biological systems is largely limited to cell and bacterial
systems. In this work, a glycoalbumin–AuIII complex was designed and developed that …

Artificial metalloenzymes result from anchoring an organometallic catalyst within an
evolvable protein scaffold. Thanks to its dimer of dimers quaternary structure, streptavidin …

Abstract Noble metals including Ag, Au, Pd, and Pt were widely applied in various aspects of
human social life, industrial manufacture, healthcare, and scientific research. The ion form of …

The development of synthetic, metal-based catalysts to perform intracellular bioorthogonal
reactions represents a relatively new and important area of research that combines …

The viability of building artificial metabolic pathways within a cell will depend on our ability to
design biocompatible and orthogonal catalysts capable of achieving non-natural …

This feature article discusses synthetic metal complexes that are capable of catalyzing
chemical transformations in living organisms. Photodynamic therapy exemplifies what is …